Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indolylnitroalkenes
文献类型：期刊论文
| 作者 | Xing, Junwei ; Chen, Guihua ; Cao, Peng ; Liao, Jian |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2012 |
| 期号 | 6页码:1230-1236 |
| 关键词 | Synthetic methods Asymmetric synthesis Homogeneous catalysis Rhodium Heterocycles |
| ISSN号 | 1434-193X |
| 产权排序 | 2 |
| 通讯作者 | Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China. |
| 英文摘要 | Indolylnitroethanes and their derivatives are key intermediates to many bioactive structures. Most approaches to access chiral indolylnitroethanes involve organocatalyzed or metal-catalyzed asymmetric FriedelCrafts reaction of indoles with nitroalkenes. We have developed an efficient approach to optically pure a-aryl-3-indolylnitroethanes through rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to indolylnitroalkenes. Excellent yields (up to 99?%) and enantiomeric excesses (up to 99?% ee) of chiral indolylnitroethanes were achieved under mild conditions. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China (NSFC) [21072186, 20872139]; West Light Foundation of CAS; National Basic Research Program of China (973 Program) [2010CB833300]; Chengdu Institute of Biology, CAS [Y0B1051100] |
| 语种 | 英语 |
| WOS记录号 | WOS:000300499000025 |
| 公开日期 | 2013-07-03 |
| 源URL | [http://210.75.237.14/handle/351003/23915]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | Xing, Junwei,Chen, Guihua,Cao, Peng,et al. Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indolylnitroalkenes[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(6):1230-1236. |
| APA | Xing, Junwei,Chen, Guihua,Cao, Peng,&Liao, Jian.(2012).Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indolylnitroalkenes.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(6),1230-1236. |
| MLA | Xing, Junwei,et al."Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Indolylnitroalkenes".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .6(2012):1230-1236. |
入库方式： OAI收割
来源：成都生物研究所
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