Cobalt-catalyzed C(sp(3))-H/C(sp(2))-H oxidative coupling between alkanes and benzamides
文献类型：期刊论文
| 作者 | Li, Shuangjie1,2,3; Wang, Bao1,3,4; Dong, Guangyu1,3,4; Li, Chunpu1,3; Liu, Hong1,3
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:24页码:13454-13458 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c8ra01377b |
| 文献子类 | Article |
| 英文摘要 | A direct cobalt-catalyzed oxidative coupling between C(sp(2))-H in unactivated benzamides and C(sp(3))-H in simple alkanes, ethers and toluene derivatives was explored. This protocol achieves direct C-C formation without using alkyl or aryl halide surrogates and exhibits high practicality with ample substrate scope. The method provides a new way to construct linear and five- or six-membered ring moieties in bioactive molecules. |
| WOS关键词 | SINGLE-ELECTRON TRANSMETALATION ; NONACTIVATED ALKYL-HALIDES ; N-QUINOLYL BENZAMIDES ; C-H FUNCTIONALIZATION ; METAL-FREE ; METHYLATING REAGENT ; C(SP(3))-H BONDS ; NICKEL CATALYSIS ; DICUMYL PEROXIDE ; DIRECTING GROUP |
| 资助项目 | National Natural Science Foundation of China[81620108027] ; National Natural Science Foundation of China[81220108025] ; National Natural Science Foundation of China[21632008] ; National Natural Science Foundation of China[21602234] ; National Natural Science Foundation of China[81602975] ; Major Project of Chinese National Programs for Fundamental Research and Development[2015CB910304] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000430018700048 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/272317]  |
| 专题 | 药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Liu, Hong |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Receptor Res, Shanghai Inst Mat Med, 555 Chong Zhi Rd, Shanghai, Peoples R China; 2.China Pharmaceut Univ, Sch Pharm, Nanjing 210009, Jiangsu, Peoples R China; 3.Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, 555 Chong Zhi Rd, Shanghai 201203, Peoples R China; 4.ShanghaiTech Univ, Sch Life Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shuangjie,Wang, Bao,Dong, Guangyu,et al. Cobalt-catalyzed C(sp(3))-H/C(sp(2))-H oxidative coupling between alkanes and benzamides[J]. RSC ADVANCES,2018,8(24):13454-13458. |
| APA | Li, Shuangjie,Wang, Bao,Dong, Guangyu,Li, Chunpu,&Liu, Hong.(2018).Cobalt-catalyzed C(sp(3))-H/C(sp(2))-H oxidative coupling between alkanes and benzamides.RSC ADVANCES,8(24),13454-13458. |
| MLA | Li, Shuangjie,et al."Cobalt-catalyzed C(sp(3))-H/C(sp(2))-H oxidative coupling between alkanes and benzamides".RSC ADVANCES 8.24(2018):13454-13458. |
入库方式： OAI收割
来源：上海药物研究所
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