Transformation of aryl acyloin O-alkyl and O-phenyl derivatives to ketones
文献类型：期刊论文
| 作者 | Yao, Zhiyi; Ye, Deju; Liu, Hong ; Chen, Kaixian
|
| 刊名 | SYNTHETIC COMMUNICATIONS
 |
| 出版日期 | 2007 |
| 卷号 | 37期号:1-3页码:149-156 |
| 关键词 | aryl acyloin O-derivatives deoxygenation 2,2-dialkoxy-1-phenyl ethanone alpha,beta-epoxy ketones |
| ISSN号 | 0039-7911 |
| DOI | 10.1080/00397910600978564 |
| 文献子类 | Article |
| 英文摘要 | The treatment of aryl acyloin (a-hydroxyketone) O-alkyl and O-phenyl derivatives with 2-3 equiv of Zn and 1-2 equiv of NH4Cl in ethanol, refluxing for 20-120 min, gave the corresponding ketones with excellent yields. Further, alpha,beta-epoxy ketones can be efficiently transformed to beta-hydroxy ketones, and 2,2-dialkoxy-1-phenyl ketone also can be dealkoxylated to 1-phenyl ketone. |
| WOS关键词 | PROTECTING GROUPS ; ACETOPHENONE ; SANTONIN ; SYSTEM ; ACID |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000247620200017 |
| 出版者 | TAYLOR & FRANCIS INC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/273421]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Liu, Hong |
| 作者单位 | 1.Chinese Acad Sci, Grad Sch, Shanghai, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China 3.Chinese Acad Sci, Inst Biol Sci, Ctr Drug Discovery & Design, State Key Lav Drug Res, Shanghai, Peoples R China 4.E China Univ Sci & Technol, Sch Pharm, Shanghai, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Zhiyi,Ye, Deju,Liu, Hong,et al. Transformation of aryl acyloin O-alkyl and O-phenyl derivatives to ketones[J]. SYNTHETIC COMMUNICATIONS,2007,37(1-3):149-156. |
| APA | Yao, Zhiyi,Ye, Deju,Liu, Hong,&Chen, Kaixian.(2007).Transformation of aryl acyloin O-alkyl and O-phenyl derivatives to ketones.SYNTHETIC COMMUNICATIONS,37(1-3),149-156. |
| MLA | Yao, Zhiyi,et al."Transformation of aryl acyloin O-alkyl and O-phenyl derivatives to ketones".SYNTHETIC COMMUNICATIONS 37.1-3(2007):149-156. |
入库方式： OAI收割
来源：上海药物研究所
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