Crystal and mol-ecular structure of jatrophane diterpenoid (2R,3R,4S,5R,7S,8S,9S,13S,14S,15R)-2,3,8,9-tetra-acet-oxy-5,14-bis-(benzo-yloxy)-15-hydroxy-7-(iso-butano-yloxy)jatropha-6(17),11(E)-diene.
文献类型：期刊论文
| 作者 | Yang, Hequn; Zhao, Jiangyu ; Talipov, Samat; Izotova, Lidiya; Aisa, Haji Akber; Ibragimov, Bakhtiyar
|
| 刊名 | Acta crystallographica. Section E, Crystallographic communications
 |
| 出版日期 | 2019 |
| 卷号 | 75期号:Pt12页码:1884-1887 |
| ISSN号 | 2056-9890 |
| 英文摘要 | The structure of the jatrophane diterpenoid (ES2), C46H56O15, has ortho-rhom-bic (P212121) symmetry. The absolute configuration in the crystal has been determined as 2R,3R,4S,5R,7S,8S,9S,13S,14S,15R [the Flack parameter is -0.06 (11)]. The mol-ecular structure features intra-molecular O-H⋯O and C-H⋯O hydrogen bonding. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into supra-molecular columns parallel to the a axis. One of the acet-oxy substituents is disordered over two orientations in a 0.826 (8):0.174 (8) ratio. |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/7194]  |
| 专题 | 新疆理化技术研究所_省部共建新疆特有药用资源利用重点实验室 新疆理化技术研究所_资源化学研究室 |
| 作者单位 | 1.Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, H. Abdullaev Str, 83, Tashkent, 100125, Uzbekistan. 2.Key Laboratory of Plant Resources and Chemistry of Arid Zones, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Science, Urumqi 830011, People's Republic of China |
| 推荐引用方式 GB/T 7714 | Yang, Hequn,Zhao, Jiangyu,Talipov, Samat,et al. Crystal and mol-ecular structure of jatrophane diterpenoid (2R,3R,4S,5R,7S,8S,9S,13S,14S,15R)-2,3,8,9-tetra-acet-oxy-5,14-bis-(benzo-yloxy)-15-hydroxy-7-(iso-butano-yloxy)jatropha-6(17),11(E)-diene.[J]. Acta crystallographica. Section E, Crystallographic communications,2019,75(Pt12):1884-1887. |
| APA | Yang, Hequn,Zhao, Jiangyu,Talipov, Samat,Izotova, Lidiya,Aisa, Haji Akber,&Ibragimov, Bakhtiyar.(2019).Crystal and mol-ecular structure of jatrophane diterpenoid (2R,3R,4S,5R,7S,8S,9S,13S,14S,15R)-2,3,8,9-tetra-acet-oxy-5,14-bis-(benzo-yloxy)-15-hydroxy-7-(iso-butano-yloxy)jatropha-6(17),11(E)-diene..Acta crystallographica. Section E, Crystallographic communications,75(Pt12),1884-1887. |
| MLA | Yang, Hequn,et al."Crystal and mol-ecular structure of jatrophane diterpenoid (2R,3R,4S,5R,7S,8S,9S,13S,14S,15R)-2,3,8,9-tetra-acet-oxy-5,14-bis-(benzo-yloxy)-15-hydroxy-7-(iso-butano-yloxy)jatropha-6(17),11(E)-diene.".Acta crystallographica. Section E, Crystallographic communications 75.Pt12(2019):1884-1887. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。