In situ construction of biocompatible Z-scheme alpha-Bi2O3/CuBi2O4 heterojunction for NO removal under visible light
文献类型:期刊论文
作者 | Chen, Qian4; Long, Huimin4; Chen, Meijuan1; Rao, Yongfang4; Li, Xinwei2,3; Huang, Yu3,5 |
刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL |
出版日期 | 2020-09-05 |
卷号 | 272页码:8 |
ISSN号 | 0926-3373 |
关键词 | In situ synthesis Z-scheme heterojunction Photocatalytic NO removal In situ DRIFTS Cytotoxicity |
DOI | 10.1016/j.apcatb.2020.119008 |
通讯作者 | Rao, Yongfang(yfrao@mail.xjtu.edu.cn) ; Huang, Yu(huangyu@ieecas.cn) |
英文摘要 | The design of efficient, stable and biocompatible photocatalysts for air purification is still a challenge. In this work, we report a Z-scheme alpha-Bi2O3/CuBi2O4 composite with high-quality interfaces using an in situ synthesis method. The alpha-Bi2O3/CuBi2O4 displays significantly enhanced photocatalytic activity for NO removal (30 %) in comparison with alpha-Bi2O3 (17 %) under visible light irradiation. Based on characterizations, theoretical calculations and ESR tests, the Z-scheme migration mechanism of photoinduced electrons and holes on alpha-Bi2O3/CuBi2O4 heterojunction was proposed. The formation of intermediates and products was monitored by in situ DRIFTS. The NO adsorption and activation on alpha-Bi2O3/CuBi2O4 surface are more favorable than that on alpha-Bi2O3 surface. The alpha-Bi2O3/CuBi2O4 also shows high selectivity for the conversion of NO to NO- 3. Moreover, the cytotoxicity of alpha-Bi2O3/CuBi2O4 exposed to human alveolar epithelial cell has been evaluated for its potential application in air purification. This work provides a new perspective regarding the design of Z-scheme heterojunctions by an in situ method and a promising photocatalyst suitable for air pollution control. |
WOS关键词 | SELF-SACRIFICIAL SYNTHESIS ; PHOTOCATALYTIC NO ; BI METAL ; CHARGE-TRANSFER ; ELECTRIC-FIELD ; PERFORMANCE ; OXIDE ; MECHANISM ; TETRACYCLINE ; DEGRADATION |
资助项目 | Key Laboratory of Aerosol Chemistry and Physics, Institute of Earth Environment, CAS[KLACP1701] ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, CAS[SKLLQG1516] |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000533148700031 |
资助机构 | Key Laboratory of Aerosol Chemistry and Physics, Institute of Earth Environment, CAS ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, CAS |
源URL | [http://ir.ieecas.cn/handle/361006/14000] |
专题 | 中国科学院地球环境研究所 |
通讯作者 | Rao, Yongfang; Huang, Yu |
作者单位 | 1.Xi An Jiao Tong Univ, Sch Human Settlements & Civil Engn, Xian 710049, Peoples R China 2.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong, Peoples R China 3.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol SKLLQG, Xian 710075, Peoples R China 4.Xi Jiaotong Univ, Dept Environm Sci & Engn, Xian 710049, Peoples R China 5.Chinese Acad Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, Xian 710075, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Qian,Long, Huimin,Chen, Meijuan,et al. In situ construction of biocompatible Z-scheme alpha-Bi2O3/CuBi2O4 heterojunction for NO removal under visible light[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2020,272:8. |
APA | Chen, Qian,Long, Huimin,Chen, Meijuan,Rao, Yongfang,Li, Xinwei,&Huang, Yu.(2020).In situ construction of biocompatible Z-scheme alpha-Bi2O3/CuBi2O4 heterojunction for NO removal under visible light.APPLIED CATALYSIS B-ENVIRONMENTAL,272,8. |
MLA | Chen, Qian,et al."In situ construction of biocompatible Z-scheme alpha-Bi2O3/CuBi2O4 heterojunction for NO removal under visible light".APPLIED CATALYSIS B-ENVIRONMENTAL 272(2020):8. |
入库方式: OAI收割
来源:地球环境研究所
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