Novel N/Carbon Quantum Dot Modified MIL-125(Ti) Composite for Enhanced Visible-Light Photocatalytic Removal of NO
文献类型：期刊论文
| 作者 | Chen, Meijuan1,2,3; Wei, Xiaoyan2; Zhao, Liaoliao2,4; Huang, Yu2; Lee, Shun-cheng5; Ho, Wingkei6; Chen, Kehao3 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2020-04-08 |
| 卷号 | 59期号:14页码:6470-6478 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.9b06816 |
| 通讯作者 | Chen, Meijuan(chenmeijuan@xjtu.edu.cn) ; Huang, Yu(huangyu@ieecas.cn) |
| 英文摘要 | Highly efficient and stable photocatalysts were synthesized at room temperature by modifying MIL-125(Ti) with N-doped carbon quantum dots (N/CM(Ti)). The N/CM(Ti) with 2.5 vol % N doped carbon quantum dots (N/CQDs) had the best light absorption and visible-light photocatalytic nitrogen oxide (NO) removal efficiency (approximately 49%). It was found through X-ray photoelectron spectroscopy analysis that a N-Ti-O bond was formed in the 2.5 vol % N/CM(Ti), which is more conducive to charge transfer. Photocurrent and electrochemical impedance data also showed that the carrier separation efficiency of 2.5 vol % N/CM(Ti) was significantly superior to that of MIL-125(Ti). In addition, the Ti-III-Ti-IV of MIL-125(Ti) acts as the active center for photocatalytic removal of NO. Two possible electron migration paths were proposed: electron transfer from N/CQDs to Ti-III-Ti-IV center of MIL-125(Ti) due to the photoinduced electron transfer property of N/CQDs, and absorption of UV light generated from the N/CQDs by the terephthalic acid ligand followed by electron transfer to metal active sites for photocatalytic removal of NO. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; CARBON NITRIDE ; WASTE-WATER ; ADSORPTION ; STABILITY ; EVOLUTION ; HYDROGEN ; OXIDE |
| 资助项目 | National Science Foundation of China[41877481] ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, CAS[SKLLQG1729] ; Fundamental Research Funds for the Central Universities[xjj2018249] ; Opening Fund of Key Laboratory of Degraded and Unused Land Consolidation Engineering, the Ministry of Natural Resources[SXDJ2019-15] ; China Postdoctoral Science Foundation[2018M643669] ; National Key Research and Development Program of China[2016YFA0203000] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000526422700011 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Science Foundation of China ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, CAS ; Fundamental Research Funds for the Central Universities ; Opening Fund of Key Laboratory of Degraded and Unused Land Consolidation Engineering, the Ministry of Natural Resources ; China Postdoctoral Science Foundation ; National Key Research and Development Program of China |
| 源URL | [http://ir.ieecas.cn/handle/361006/12584]  |
| 专题 | 地球环境研究所_粉尘与环境研究室 |
| 通讯作者 | Chen, Meijuan; Huang, Yu |
| 作者单位 | 1.Xi An Jiao Tong Univ, Sch Human Settlements & Civil Engn, Xian 710049, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, SKLLQG, Key Lab Aerosol Chem & Phys, Xian 710061, Peoples R China 3.Minist Nat Resources China, Key Lab Degraded & Unused Land Consolidat Engn, Xian 710075, Peoples R China 4.Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Peoples R China 5.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong 999077, Peoples R China 6.Educ Univ Hong Kong, Dept Sci & Environm Studies, Hong Kong 999077, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Meijuan,Wei, Xiaoyan,Zhao, Liaoliao,et al. Novel N/Carbon Quantum Dot Modified MIL-125(Ti) Composite for Enhanced Visible-Light Photocatalytic Removal of NO[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(14):6470-6478. |
| APA | Chen, Meijuan.,Wei, Xiaoyan.,Zhao, Liaoliao.,Huang, Yu.,Lee, Shun-cheng.,...&Chen, Kehao.(2020).Novel N/Carbon Quantum Dot Modified MIL-125(Ti) Composite for Enhanced Visible-Light Photocatalytic Removal of NO.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(14),6470-6478. |
| MLA | Chen, Meijuan,et al."Novel N/Carbon Quantum Dot Modified MIL-125(Ti) Composite for Enhanced Visible-Light Photocatalytic Removal of NO".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.14(2020):6470-6478. |
入库方式： OAI收割
来源：地球环境研究所
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