中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Secondary organic aerosol enhanced by increasing atmospheric oxidizing capacity in Beijing-Tianjin-Hebei (BTH), China

文献类型:期刊论文

作者Feng, Tian2,4,5; Zhao, Shuyu4,6; Bei, Naifang1; Wu, Jiarui4,6; Liu, Suixin4,6; Li, Xia4,6; Liu, Lang4,6; Qian, Yang3; Yang, Qingchuan6; Wang, Yichen6
刊名ATMOSPHERIC CHEMISTRY AND PHYSICS
出版日期2019-06-05
卷号19期号:11页码:7429-7443
ISSN号1680-7316
DOI10.5194/acp-19-7429-2019
英文摘要

The implementation of the Air Pollution Prevention and Control Action Plan in China since 2013 has profoundly altered the ambient pollutants in the Beijing-Tianjin-Hebei (BTH) region. Here we show observations of substantially increased O-3 concentrations (about 30 %) and a remarkable increase in the ratio of organic carbon (OC) to elemental carbon (EC) in BTH during the autumn from 2013 to 2015, revealing an enhancement in atmospheric oxidizing capacity (AOC) and secondary organic aerosol (SOA) formation. To explore the impacts of increasing AOC on the SOA formation, a severe air pollution episode from 3 to 8 October 2015 with high O-3 and PM2.5 concentrations is simulated using the WRF-Chem model. The model performs reasonably well in simulating the spatial distributions of PM2.5 and O-3 concentrations over BTH and the temporal variations in PM2.5, O-3, NO2, OC, and EC concentrations in Beijing compared to measurements. Sensitivity studies show that the change in AOC substantially influences the SOA formation in BTH. A sensitivity case characterized by a 31 % 03 decrease (or 36 % OH decrease) reduces the SOA level by about 30 % and the SOA fraction in total organic aerosol by 17 % (from 0.52 to 0.43, dimensionless). Spatially, the SOA decrease caused by reduced AOC is ubiquitous in BTH, but the spatial relationship between SOA concentrations and the AOC is dependent on the SOA precursor distribution. Studies on SOA formation pathways further show that when the AOC is reduced, the SOA from oxidation and partitioning of semivolatile primary organic aerosol (POA) and coemitted intermediate volatile organic compounds (IVOCs) decreases remarkably, followed by those from anthropogenic and biogenic volatile organic compounds (VOCs). Meanwhile, the SOA decrease in the irreversible uptake of glyoxal and methylglyoxal on the aerosol surfaces is negligible.

WOS关键词MEXICO-CITY ; METEOROLOGICAL UNCERTAINTIES ; AIR-QUALITY ; HAZE FORMATION ; HONO SOURCES ; MODEL ; EMISSIONS ; POLLUTION ; SIMULATIONS ; WINTERTIME
资助项目National Key R&D Plan (Quantitative Relationship and Regulation Principle between Regional Oxidation Capacity of Atmospheric and Air Quality)[2017YFC0210000] ; National Research Program for Key Issues in Air Pollution Control[DQGG0105] ; National Natural Science Foundation of China[41703127] ; National Natural Science Foundation of China[41430424] ; National Natural Science Foundation of China[41661144020]
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
语种英语
出版者COPERNICUS GESELLSCHAFT MBH
WOS记录号WOS:000470732300002
资助机构National Key R&D Plan (Quantitative Relationship and Regulation Principle between Regional Oxidation Capacity of Atmospheric and Air Quality) ; National Research Program for Key Issues in Air Pollution Control ; National Natural Science Foundation of China
源URL[http://ir.ieecas.cn/handle/361006/13891]  
专题地球环境研究所_粉尘与环境研究室
通讯作者Li, Guohui
作者单位1.Xi An Jiao Tong Univ, Sch Human Settlements & Civil Engn, Xian, Shaanxi, Peoples R China
2.Xian Accelerator Mass Spectrometry Ctr, Xian, Shaanxi, Peoples R China
3.Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing, Peoples R China
4.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian, Shaanxi, Peoples R China
5.Ningbo Univ, Dept Geog & Spatial Informat Tech, Ningbo, Zhejiang, Peoples R China
6.Chinese Acad Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, Xian, Shaanxi, Peoples R China
7.CAS Ctr Excellence Quaternary Sci & Global Change, Xian, Shaanxi, Peoples R China
推荐引用方式
GB/T 7714
Feng, Tian,Zhao, Shuyu,Bei, Naifang,et al. Secondary organic aerosol enhanced by increasing atmospheric oxidizing capacity in Beijing-Tianjin-Hebei (BTH), China[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2019,19(11):7429-7443.
APA Feng, Tian.,Zhao, Shuyu.,Bei, Naifang.,Wu, Jiarui.,Liu, Suixin.,...&Li, Guohui.(2019).Secondary organic aerosol enhanced by increasing atmospheric oxidizing capacity in Beijing-Tianjin-Hebei (BTH), China.ATMOSPHERIC CHEMISTRY AND PHYSICS,19(11),7429-7443.
MLA Feng, Tian,et al."Secondary organic aerosol enhanced by increasing atmospheric oxidizing capacity in Beijing-Tianjin-Hebei (BTH), China".ATMOSPHERIC CHEMISTRY AND PHYSICS 19.11(2019):7429-7443.

入库方式: OAI收割

来源:地球环境研究所

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