With the purpose of investigate the characteristics and provenances of the hazardous trace elements (HTEs) in a typical agricultural land in the undulating plain area of eastern Anhui province, China, a total of 1170 soil samples were collected. Six HTEs, including Cd, Cr, Hg, Ni, Pb, and As, were determined. Statistical methods including box plot, Pearson correlation analysis, principal component analysis, and cluster analysis, were conducted to illustrate the provenances of HTEs. Results indicate that Cd and Hg were influenced by human activities (such as traffic transportation for Cd and Pb, and chemical pesticides for Hg). Cr, Ni, and As mainly originated from the parent materials (e.g., red detrital rocks, carbonate rocks, and late Pleistocene loess). Pb is of dual provenances of both human activity and parent material. In a word, regarding highly toxic HTEs, the soil in the study area is almost free from pollution, and only a small amount of soil samples contains slightly higher contents of As, Cd and Pb.