Effects of different cone combinations on accurate and precise determination of Li isotopic composition by MC-ICP-MS
文献类型：期刊论文
| 作者 | Gou, Long-Fei2,3; Jin, Zhang-Dong1,2; Deng, Li2; He, Mao-Yong2; Liu, Chun-Yao2,3 |
| 刊名 | SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
 |
| 出版日期 | 2018-08-01 |
| 卷号 | 146页码:1-8 |
| 关键词 | Lithium isotopes Cone combination Mass bias MC-ICP-MS |
| ISSN号 | 0584-8547 |
| DOI | 10.1016/j.sab.2018.04.015 |
| 通讯作者 | Jin, Zhang-Dong(zhdjin@ieecas.cn) |
| 英文摘要 | The multiple collector inductively coupled plasma mass spectrometer (MC-ICP-MS) is booming to be a high-precision, fast, and accurate instrument in measuring lithium (Li) isotopes. Modified highly sensitive Jet sample and X skimmer cones have largely upgraded analytical sensitivity and reduced sample consumption with distinct instrumental mass bias behaviors. Herein, four available combinations of the sample and skimmer cones [Jet sample cone + X skimmer cone (Jet + X), Standard sample cone + X skimmer cone (Standard + X), Standard sample cone + H skimmer cone (Standard + H), and Jet sample cone + H skimmer cone (Jet + H)] were tested for their effects on peak shape, sensitivity, mass bias behavior, and accuracy and precision of Li isotopic measurements in solution mode. The results showed that all four combinations were able to attain an ideal peak shape by adjusting the associated parameters, with a positively linear relation between Li-7 (and Li-6) signals and Li concentrations. For a given Li concentration, the sensitivities were enhanced 3-7 times using the Standard + X, the Jet + H, and the Jet +X combinations compared to that of using the Standard + H. The enhanced sensitivity is attributable to more plasma ions introduced into the mass spectrometer through the Jet and X cones. Mass bias is distinct for different cone combinations, with a slight difference with various Li concentrations, indicating the neccesity of concentration match during measurement. Among the four cone combinations, the best reproducibility can be obtained by using the Standard + X cones to determine precise and accurate Li isotopes for samples. Furthermore, a pretreatment by 5% HNO3 and 0.1% HF, and then 2% HNO3 prior to analyses can minimize the memory effect of Li. (C) 2018 Elsevier B.V. All rights reserved. |
| WOS关键词 | PLASMA-MASS SPECTROMETRY ; GEOLOGICAL-MATERIALS ; RATIO ANALYSIS ; LITHIUM ; FRACTIONATION ; SYSTEMATICS ; CONSTRAINTS ; SAMPLES ; MANTLE ; BORON |
| 资助项目 | National Natural Science Foundation of China[41773149] |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000439675300001 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ieecas.cn/handle/361006/13240]  |
| 专题 | 地球环境研究所_加速器质谱中心 |
| 通讯作者 | Jin, Zhang-Dong |
| 作者单位 | 1.Xi An Jiao Tong Univ, Inst Global Environm Change, Xian 710049, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710061, Shaanxi, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gou, Long-Fei,Jin, Zhang-Dong,Deng, Li,et al. Effects of different cone combinations on accurate and precise determination of Li isotopic composition by MC-ICP-MS[J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY,2018,146:1-8. |
| APA | Gou, Long-Fei,Jin, Zhang-Dong,Deng, Li,He, Mao-Yong,&Liu, Chun-Yao.(2018).Effects of different cone combinations on accurate and precise determination of Li isotopic composition by MC-ICP-MS.SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY,146,1-8. |
| MLA | Gou, Long-Fei,et al."Effects of different cone combinations on accurate and precise determination of Li isotopic composition by MC-ICP-MS".SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY 146(2018):1-8. |
入库方式： OAI收割
来源：地球环境研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。