Evaluation of the sealed-tube low-temperature combustion method for the C-13/C-12 and H-2/H-1 ratio determinations of cellulose nitrate
文献类型：期刊论文
| 作者 | Tao, FX; Aucour, AM; Sheppard, SMF; Liu, CQ; Leng, XT; Wang, SL; Liu, GS; Xu, WB |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2001-11 |
| 卷号 | 19期号:11页码:1089-1096 |
| 关键词 | carbon isotope hydrogen isotope cellulose nitrate sealed-tube combustion nitrous oxide |
| 文献子类 | Article |
| 英文摘要 | Traditionally-suggested combustion time of 1 h at 550degreesC with the sealed-tube combustion method for determining the C-13/C-12 ratio of cellulose nitrate or other nitrogen-containing components could produce large negative deviation up to 1%.. Three types of cellulose are used to ascertain possible causes. The presence of nitrous oxide (N2O) formed during combustion is most likely responsible for this deviation. Prolongation of the combustion time (at least 5 h at 550degreesC) and intimate contact between copper oxide and organic matter can greatly improve the analysis precision and effectively reduce this deviation to an acceptable level. Regardless of scattered carbon isotope data, hydrogen isotope data are all reproducible within 2% when this method is coupled with the high temperature uranium reduction method. Thus, care should be taken for determining carbon and nitrogen isotope compositions of nitrogen-containing substances using the low temperature sealed-tube combustion method. |
| 学科主题 | Chemistry |
| WOS关键词 | CARBON ISOTOPE ANALYSIS ; CLIMATIC IMPLICATIONS ; ORGANIC-MATTER ; D/H RATIOS ; HYDROGEN ; WATER ; FRACTIONS ; RINGS ; WOOD |
| WOS研究方向 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000173220900014 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.ieecas.cn/handle/361006/12072]  |
| 专题 | 黄土与第四纪地质国家重点实验室（1985-2004） |
| 推荐引用方式 GB/T 7714 | Tao, FX,Aucour, AM,Sheppard, SMF,et al. Evaluation of the sealed-tube low-temperature combustion method for the C-13/C-12 and H-2/H-1 ratio determinations of cellulose nitrate[J]. CHINESE JOURNAL OF CHEMISTRY,2001,19(11):1089-1096. |
| APA | Tao, FX.,Aucour, AM.,Sheppard, SMF.,Liu, CQ.,Leng, XT.,...&Xu, WB.(2001).Evaluation of the sealed-tube low-temperature combustion method for the C-13/C-12 and H-2/H-1 ratio determinations of cellulose nitrate.CHINESE JOURNAL OF CHEMISTRY,19(11),1089-1096. |
| MLA | Tao, FX,et al."Evaluation of the sealed-tube low-temperature combustion method for the C-13/C-12 and H-2/H-1 ratio determinations of cellulose nitrate".CHINESE JOURNAL OF CHEMISTRY 19.11(2001):1089-1096. |
入库方式： OAI收割
来源：地球环境研究所
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