Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins
文献类型：期刊论文
| 作者 | Dong, Guangyu1,2,3; Li, Chunpu1; Liu, Hong1,2,3
|
| 刊名 | MOLECULES
 |
| 出版日期 | 2019-03-01 |
| 卷号 | 24期号:5页码:19 |
| 关键词 | rhodium annulation Boc-protected benzamides |
| ISSN号 | 1420-3049 |
| DOI | 10.3390/molecules24050937 |
| 通讯作者 | Liu, Hong(hliu@simm.ac.cn) |
| 英文摘要 | A mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C-C/C-O bond formation has been explored. In the presence of [Cp*RhCl2](2), AgSbF6 and Cs2CO3, Boc-protected benzamides can be effectively annulated to yield isocoumarins in 0.5-2 h. |
| WOS关键词 | ALPHA-PYRONES ; CATALYZED-REACTIONS ; BOND FORMATION ; BENZOIC-ACIDS ; C-C ; CYCLIZATION ; AMIDES ; OXIDATION ; ALKYNES ; LIGAND |
| 资助项目 | National Natural Science Foundation of China[81620108027] ; National Natural Science Foundation of China[21632008] ; National Natural Science Foundation of China[21672231] ; Major Project of Chinese National Programs for Fundamental Research and Development[2015CB910304] |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000462662900113 |
| 出版者 | MDPI |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/290122]  |
| 专题 | 新药研究国家重点实验室 |
| 通讯作者 | Liu, Hong |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zuchongzhi Rd, Shanghai 201203, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 3.ShanghaiTech Univ, Sch Life Sci & Technol, 100 Haike Rd, Shanghai 201210, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Guangyu,Li, Chunpu,Liu, Hong. Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins[J]. MOLECULES,2019,24(5):19. |
| APA | Dong, Guangyu,Li, Chunpu,&Liu, Hong.(2019).Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins.MOLECULES,24(5),19. |
| MLA | Dong, Guangyu,et al."Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins".MOLECULES 24.5(2019):19. |
入库方式： OAI收割
来源：上海药物研究所
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