A mechanistic study of electrode materials for rechargeable batteries beyond lithium ions by in situ transmission electron microscopy
文献类型：期刊论文
| 作者 | Yousaf, Muhammad1,2,3; Naseer, Ufra4; Li, Yiju3,5; Ali, Zeeshan5,6; Mahmood, Nasir7; Wang, Lei8; Gao, Peng1,2; Guo, Shaojun3,5 |
| 刊名 | ENERGY & ENVIRONMENTAL SCIENCE
 |
| 出版日期 | 2021-02-22 |
| 页码 | 38 |
| ISSN号 | 1754-5692 |
| DOI | 10.1039/d0ee03295f |
| 通讯作者 | Gao, Peng(pengg@pku.edu.cn) ; Guo, Shaojun(guosj@pku.edu.cn) |
| 英文摘要 | Understanding the fundamental mechanisms of advanced electrode materials at the atomic scale during the electrochemical process is necessary to develop high-performance rechargeable batteries. The complex electrochemical reactions involved in a running battery, which cause intensive structural and morphological changes in electrode materials, have been explored to a certain extent by the use of real-time characterization techniques. In situ transmission electron microscopy (TEM) is one of the most noteworthy diagnostic techniques to understand and monitor dynamic electrochemical processes because of its atomic-scale resolution and real-time monitoring, which can provide information about chemical and physical characteristics. In this review, the current progress in the development of electrode materials using in situ TEM for rechargeable batteries beyond the lithium ion is summarized. First, the various battery designs used for in situ TEM and their challenges are elaborated. Afterward, we systematically summarize the basic science and fundamental reactions including phase transformation and electrode/electrolyte interfaces in electrode materials for heavier alkali ion (sodium, potassium calcium and magnesium) batteries (H-AIBs). Particularly, the real-time insights into three types of electrochemical mechanisms: intercalation, alloying, and conversion reactions are elaborated. Moreover, in situ electrode chemistry in lithium sulfur (Li-S) batteries, alkali-metal oxygen batteries (AOBs) including lithium, sodium and potassium oxygen batteries, and all-solid-state batteries (ASSBs) is also discussed. Finally, we provide a summary and future perspective of in situ TEM in rechargeable batteries along with the most feasible electrode design. |
| 资助项目 | National Natural Science Fund for Distinguished Young Scholars[52025133] ; Tencent Foundation through the XPLORER PRIZE ; Beijing Natural Science Foundation[JQ18005] ; National Natural Science Foundation of China[51672007] ; National Natural Science Foundation of China[11974023] ; Fund of the State Key Laboratory of Solidification Processing in NWPU[SKLSP202004] ; Key Area R&D Program of Guangdong Prov.[2018B030327001] ; Key Area R&D Program of Guangdong Prov.[2018B010109009] ; RMIT Vice-Chancellor Fellowship, RMIT University, Australia |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000639551000001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Fund for Distinguished Young Scholars ; Tencent Foundation through the XPLORER PRIZE ; Beijing Natural Science Foundation ; National Natural Science Foundation of China ; Fund of the State Key Laboratory of Solidification Processing in NWPU ; Key Area R&D Program of Guangdong Prov. ; RMIT Vice-Chancellor Fellowship, RMIT University, Australia |
| 源URL | [http://ir.igsnrr.ac.cn/handle/311030/161870]  |
| 专题 | 中国科学院地理科学与资源研究所 |
| 通讯作者 | Gao, Peng; Guo, Shaojun |
| 作者单位 | 1.Peking Univ, Int Ctr Quantum Mat, Sch Phys, Beijing 100871, Peoples R China 2.Peking Univ, Electron Microscopy Lab, Sch Phys, Beijing 100871, Peoples R China 3.Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China 4.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, State Key Lab Resources & Environm Informat Syst, Beijing 100871, Peoples R China 5.Peking Univ, Coll Engn, Beijing 100871, Peoples R China 6.Natl Univ Sci & Technol NUST, Sch Chem & Mat Engn SCME, H-12, Islamabad 44000, Pakistan 7.RMIT Univ, Sch Engn, 124 La Trobe St, Melbourne, Vic 3001, Australia 8.Qingdao Univ Sci & Technol, Key Lab Ecochem Engn,Team Eco Chem Proc & Technol, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, Taishan Scholar Advantage & Characterist Discipli, Qingdao 266042, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yousaf, Muhammad,Naseer, Ufra,Li, Yiju,et al. A mechanistic study of electrode materials for rechargeable batteries beyond lithium ions by in situ transmission electron microscopy[J]. ENERGY & ENVIRONMENTAL SCIENCE,2021:38. |
| APA | Yousaf, Muhammad.,Naseer, Ufra.,Li, Yiju.,Ali, Zeeshan.,Mahmood, Nasir.,...&Guo, Shaojun.(2021).A mechanistic study of electrode materials for rechargeable batteries beyond lithium ions by in situ transmission electron microscopy.ENERGY & ENVIRONMENTAL SCIENCE,38. |
| MLA | Yousaf, Muhammad,et al."A mechanistic study of electrode materials for rechargeable batteries beyond lithium ions by in situ transmission electron microscopy".ENERGY & ENVIRONMENTAL SCIENCE (2021):38. |
入库方式： OAI收割
来源：地理科学与资源研究所
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