Stable Rhodium (IV) Oxide for Alkaline Hydrogen Evolution Reaction
文献类型：期刊论文
| 作者 | Li, Z; Feng, Y; Liang, YL; Cheng, CQ; Dong, CK; Liu, H; Du, XW |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2020 |
| 卷号 | 32期号:25页码:- |
| 关键词 | ADSORPTION ENERGY SURFACE WATER CATALYSTS ELECTROCATALYSTS TRENDS |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.201908521 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Water electrolysis in alkaline electrolyte is an attractive way toward clean hydrogen energy via the hydrogen evolution reaction (HER), whereas the sluggish water dissociation impedes the following hydrogen evolution. Noble metal oxides possess promising capability for catalyzing water dissociation and hydrogen evolution; however, they are never utilized for the HER due to the instability under the reductive potential. Here it is shown that compressive strain can stabilize RhO2 clusters and promote their catalytic activity. To this end, a strawberry-like structure with RhO2 clusters embedded in the surface layer of Rh nanoparticles is engineered, in which the incompatibility between the oxide cluster and the metal substrate causes intensive compressive strain. As such, RhO2 clusters remain stable at a reduction potential up to -0.3 V versus reversible hydrogen electrode and present an alkaline HER activity superior to commercial Pt/C. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/33150]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Tianjin Univ, Inst New Energy Mat, Sch Mat Sci & Engn, Key Lab Adv Ceram & Machining Technol,Minist Educ, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Z,Feng, Y,Liang, YL,et al. Stable Rhodium (IV) Oxide for Alkaline Hydrogen Evolution Reaction[J]. ADVANCED MATERIALS,2020,32(25):-. |
| APA | Li, Z.,Feng, Y.,Liang, YL.,Cheng, CQ.,Dong, CK.,...&Du, XW.(2020).Stable Rhodium (IV) Oxide for Alkaline Hydrogen Evolution Reaction.ADVANCED MATERIALS,32(25),-. |
| MLA | Li, Z,et al."Stable Rhodium (IV) Oxide for Alkaline Hydrogen Evolution Reaction".ADVANCED MATERIALS 32.25(2020):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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