Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization
文献类型：期刊论文
| 作者 | Lu, Linjie1; Zhang, Bingsen2; Li, Hongping1; Chao, Yanhong3; Li, Yujun1; Chen, Linlin1; Li, Huaming1; Ji, Hongbing1,4; Wu, Peiwen1; Zhu, Wenshuai1 |
| 刊名 | MOLECULAR CATALYSIS
 |
| 出版日期 | 2021-08-01 |
| 卷号 | 512页码:8 |
| ISSN号 | 2468-8231 |
| 关键词 | Electronic structure Deep eutectic solvent Hexagonal boron nitride Organic modification Oxidative desulfurization |
| DOI | 10.1016/j.mcat.2021.111757 |
| 通讯作者 | Zhu, Wenshuai(zhuws@ujs.edu.cn) |
| 英文摘要 | Tuning electronic structure of metal catalysts by organic modification is an efficient strategy for domination of their catalytic performances. However, the electronic structure tuning over metal-free catalysts remains to be a challenge. In this work, an organic modification strategy with deep eutectic solvents (DES) as organic modifier over metal-free catalysts was proposed to tune the electronic structure of hexagonal boron nitride (h-BN). Detailed experiments showed that the electronic properties of h-BN was rationally tuned by the introduced DES, in which the B atoms in h-BN were positively charged. Meanwhile, the modulated electronic properties can lower the activation energy for the generation of hydroxyl radicals (center dot OH) from hydrogen peroxide (H2O2), thus leading to a promoted catalytic performance in oxidative desulfurization. This finding may pave a new strategy for tuning metal-free catalysts with highly-active catalytic performance. |
| 资助项目 | National Nat-ural Science Foundation of China[21878133] ; National Nat-ural Science Foundation of China[21908082] ; National Nat-ural Science Foundation of China[22008094] ; Chinese Postdoctoral Science Foundation[2019M651742] ; Chinese Postdoctoral Science Foundation[2019M651743] ; Natural Science Foundation of Jiangsu Province[BK20190852] ; LiaoNing Revitalization Talents Program[XLYC1807175] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000686886000001 |
| 资助机构 | National Nat-ural Science Foundation of China ; Chinese Postdoctoral Science Foundation ; Natural Science Foundation of Jiangsu Province ; LiaoNing Revitalization Talents Program |
| 源URL | [http://ir.imr.ac.cn/handle/321006/159261]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Zhu, Wenshuai |
| 作者单位 | 1.Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Jiangsu Univ, Sch Pharm, Zhenjiang 212013, Jiangsu, Peoples R China 4.Sun Yat sen Univ, Sch Chem, Fine Chem Ind Res Inst, Guangzhou 510275, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Linjie,Zhang, Bingsen,Li, Hongping,et al. Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization[J]. MOLECULAR CATALYSIS,2021,512:8. |
| APA | Lu, Linjie.,Zhang, Bingsen.,Li, Hongping.,Chao, Yanhong.,Li, Yujun.,...&Zhu, Wenshuai.(2021).Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization.MOLECULAR CATALYSIS,512,8. |
| MLA | Lu, Linjie,et al."Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization".MOLECULAR CATALYSIS 512(2021):8. |
入库方式： OAI收割
来源：金属研究所
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