Sulfoximines Assisted Rh(III)-Catalyzed C-H Activation/Annulation Cascade to Synthesize Highly Fused Indeno-1,2-benzothiazines
文献类型:期刊论文
作者 | Li, Jian1,2; Li, Hui1,2; Fang, Daqing2; Liu, Lingjun2; Han, Xu2; Sun, Jina2,3; Li, Chunpu2; Zhou, Yu2,3![]() ![]() |
刊名 | JOURNAL OF ORGANIC CHEMISTRY
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出版日期 | 2021-11-05 |
卷号 | 86期号:21页码:15217-15227 |
ISSN号 | 0022-3263 |
DOI | 10.1021/acs.joc.1c01820 |
通讯作者 | Ye, Deju(dejuye@nju.edu.cn) ; Liu, Hong(hliu@simm.ac.cn) |
英文摘要 | A facile access to highly fused tetracyclic indeno-1,2-benzothiazines has been established via a Rh(III)-catalyzed C-H bond activation and intramolecular annulation cascade between sulfoximides and all-carbon diazo indandiones. This strategy is characterized by the fact that the diazo coupling partners do not require preactivation, along with its high efficiency, broad substrate generality, and facile transformation. Particularly, the highly conjugated tetracyclic products demonstrate good optical properties and can easily enter cells to emit bright fluorescence for live cell imaging. |
WOS关键词 | CATALYZED OXIDATIVE ANNULATION ; DIAZO-COMPOUNDS ; BOND FORMATION ; CARBENOID FUNCTIONALIZATION ; ACTIVATION ; ACCESS ; 1,2-BENZOTHIAZINES ; BENZOTHIAZINES ; BENZYLAMINES ; DERIVATIVES |
资助项目 | National Natural Science Foundation of China[21632008] ; National Natural Science Foundation of China[21877118] ; National Natural Science Foundation of China[81620108027] ; National Natural Science Foundation of China[91953108] ; Science Technology Commission of Shanghai Municipality[18JC1411304] ; Science Technology Commission of Shanghai Municipality[18431907100] ; SASIBS Scholarship Program ; Youth Innovation Promotion Association CAS |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000716778300076 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://119.78.100.183/handle/2S10ELR8/299042] ![]() |
专题 | 新药研究国家重点实验室 |
通讯作者 | Ye, Deju; Liu, Hong |
作者单位 | 1.Nanjing Univ Chinese Med, Sch Chinese Mat Med, Nanjing 210023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210023, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jian,Li, Hui,Fang, Daqing,et al. Sulfoximines Assisted Rh(III)-Catalyzed C-H Activation/Annulation Cascade to Synthesize Highly Fused Indeno-1,2-benzothiazines[J]. JOURNAL OF ORGANIC CHEMISTRY,2021,86(21):15217-15227. |
APA | Li, Jian.,Li, Hui.,Fang, Daqing.,Liu, Lingjun.,Han, Xu.,...&Liu, Hong.(2021).Sulfoximines Assisted Rh(III)-Catalyzed C-H Activation/Annulation Cascade to Synthesize Highly Fused Indeno-1,2-benzothiazines.JOURNAL OF ORGANIC CHEMISTRY,86(21),15217-15227. |
MLA | Li, Jian,et al."Sulfoximines Assisted Rh(III)-Catalyzed C-H Activation/Annulation Cascade to Synthesize Highly Fused Indeno-1,2-benzothiazines".JOURNAL OF ORGANIC CHEMISTRY 86.21(2021):15217-15227. |
入库方式: OAI收割
来源:上海药物研究所
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