中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance

文献类型:期刊论文

作者Yuan MZ(苑明哲); Lv HQ(吕海钦); Chen, Zhen; Zhou, Guofu; Chen ZH(陈志鸿); Wang, Xin
刊名CHEMISTRYSELECT
出版日期2017
卷号2期号:24页码:6970-6978
ISSN号2365-6549
关键词G-c3n4 Isotype Heterojunction Protonation-assisted Hydrothermal Method Photocatalytic Stability And Reusability
产权排序1
英文摘要

Carbon Nitride is considered as a promising photocatalyst material because of its unique properties such as environment-friendly, suitable band gap and high stability. However, the photocatalytic activity of pristine g-C3N4 was greatly hindered by the recombination of photo-generated electron-hole pairs. In this work, we provide an alternative method to address this problem by the construction of g-C3N4 isotype heterojunction (CNH-T/CNH-U) structure, which was successfully synthesized by a facile protonation assisted hydrothermal method. Under the irradiation of visible light (lambda > 420nm), the CNH-T/CNH-U isotype heterojunction photocatalyst displays much higher photodegradation activity of organic dyes degradation and H-2-production activity than the pure CNH-T or CNH-U sample. This remarkably improved photocatalytic performance is attributed to the successful construction of CNH-T/CNH-U isotype heterojunction associated by protonation, which results in larger surface area and the more efficient separation of photo-generated electron-hole pairs, further investigated by electron paramagnetic resonance, photoluminescence, photocurrent measurement, and a series of active species trapping experiments.

语种英语
WOS记录号WOS:000408644100007
资助机构NSFC [51602111] ; National Key R&D Program of China [2016YFB0401502] ; Talent Program of Chinese Academy Sciences, Guangdong Province [2015 A030310196] ; Pearl River S&T Nova Program of Guangzhou [201506040045] ; Guangzhou post-doctoral initial funding
源URL[http://ir.sia.cn/handle/173321/20998]  
专题沈阳自动化研究所_广州中国科学院沈阳自动化研究所分所
通讯作者Wang, Xin
作者单位1.Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangdong, 510006, PR China
2.Shenyang Institute of Automation, Guangzhou, Chinese Academy of Science, Guangzhou, 511400, PR China
推荐引用方式
GB/T 7714
Yuan MZ,Lv HQ,Chen, Zhen,et al. Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance[J]. CHEMISTRYSELECT,2017,2(24):6970-6978.
APA Yuan MZ,Lv HQ,Chen, Zhen,Zhou, Guofu,Chen ZH,&Wang, Xin.(2017).Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance.CHEMISTRYSELECT,2(24),6970-6978.
MLA Yuan MZ,et al."Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance".CHEMISTRYSELECT 2.24(2017):6970-6978.

入库方式: OAI收割

来源:沈阳自动化研究所

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