Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance
文献类型:期刊论文
作者 | Yuan MZ(苑明哲); Lv HQ(吕海钦); Chen, Zhen; Zhou, Guofu; Chen ZH(陈志鸿); Wang, Xin |
刊名 | CHEMISTRYSELECT |
出版日期 | 2017 |
卷号 | 2期号:24页码:6970-6978 |
ISSN号 | 2365-6549 |
关键词 | G-c3n4 Isotype Heterojunction Protonation-assisted Hydrothermal Method Photocatalytic Stability And Reusability |
产权排序 | 1 |
英文摘要 | Carbon Nitride is considered as a promising photocatalyst material because of its unique properties such as environment-friendly, suitable band gap and high stability. However, the photocatalytic activity of pristine g-C3N4 was greatly hindered by the recombination of photo-generated electron-hole pairs. In this work, we provide an alternative method to address this problem by the construction of g-C3N4 isotype heterojunction (CNH-T/CNH-U) structure, which was successfully synthesized by a facile protonation assisted hydrothermal method. Under the irradiation of visible light (lambda > 420nm), the CNH-T/CNH-U isotype heterojunction photocatalyst displays much higher photodegradation activity of organic dyes degradation and H-2-production activity than the pure CNH-T or CNH-U sample. This remarkably improved photocatalytic performance is attributed to the successful construction of CNH-T/CNH-U isotype heterojunction associated by protonation, which results in larger surface area and the more efficient separation of photo-generated electron-hole pairs, further investigated by electron paramagnetic resonance, photoluminescence, photocurrent measurement, and a series of active species trapping experiments. |
语种 | 英语 |
WOS记录号 | WOS:000408644100007 |
资助机构 | NSFC [51602111] ; National Key R&D Program of China [2016YFB0401502] ; Talent Program of Chinese Academy Sciences, Guangdong Province [2015 A030310196] ; Pearl River S&T Nova Program of Guangzhou [201506040045] ; Guangzhou post-doctoral initial funding |
源URL | [http://ir.sia.cn/handle/173321/20998] |
专题 | 沈阳自动化研究所_广州中国科学院沈阳自动化研究所分所 |
通讯作者 | Wang, Xin |
作者单位 | 1.Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangdong, 510006, PR China 2.Shenyang Institute of Automation, Guangzhou, Chinese Academy of Science, Guangzhou, 511400, PR China |
推荐引用方式 GB/T 7714 | Yuan MZ,Lv HQ,Chen, Zhen,et al. Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance[J]. CHEMISTRYSELECT,2017,2(24):6970-6978. |
APA | Yuan MZ,Lv HQ,Chen, Zhen,Zhou, Guofu,Chen ZH,&Wang, Xin.(2017).Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance.CHEMISTRYSELECT,2(24),6970-6978. |
MLA | Yuan MZ,et al."Facile Construction of Metal-Free g-C3N4 Isotype Heterojunction with Highly Enhanced Visible-light Photocatalytic Performance".CHEMISTRYSELECT 2.24(2017):6970-6978. |
入库方式: OAI收割
来源:沈阳自动化研究所
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