Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam
文献类型:会议论文
作者 | Rogachev, A. A.; Yarmolenko, M. A.; Rogachev, A., V; Jiang Xiaohong; Cao, Hongtao; Lysenko, E. N.; Surzhikov, A. P. |
出版日期 | 2019 |
会议日期 | JUL 18-20, 2018 |
关键词 | CONDUCTIVITY OXIDATION STABILITY ANILINE STATE |
卷号 | 483 |
DOI | 10.1016/j.apsusc.2019.03.159 |
英文摘要 | Thin conductive nanostructured polyaniline coatings were formed by the solvent-free plasma-chemical method. Non-conductive form of an emeraldine base and crystalline hydrate of dichloride or copper dibromide were used as a target. The structure and electrophysical properties of the formed coatings were studied by spectroscopic and microscopic methods. It was demonstrated that the layers represent a polymer matrix with various degree of oxidation doped by chloride or copper bromide compounds. When mixtures of an emeraldine base and copper bromide are jointly dispersed, the formation of layers with relative concentration of its oxidized chains by more than three times bigger than the layers formed by dispersion of the emeraldine base and copper chloride is observed. The proposed method allows the deposition of thin composite PANI-based coatings which have conductivity up to 10 S/cm, adjustable degree of oxidation and a molecular structure of polyaniline chains. |
学科主题 | Chemistry ; Materials Science ; Physics |
ISSN号 | 0169-4332 |
源URL | [http://ir.nimte.ac.cn/handle/174433/23326] ![]() |
专题 | 会议专题 会议专题_会议论文 |
推荐引用方式 GB/T 7714 | Rogachev, A. A.,Yarmolenko, M. A.,Rogachev, A., V,et al. Structure and electrical properties of polyaniline-based copper chloride or copper bromide coatings deposited via low-energy electron beam[C]. 见:. JUL 18-20, 2018. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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