Optical and electrochromic properties of sol-gel deposited mixed MoO3-WO3 thin films
文献类型:会议论文
作者 | Sun, Xilian; Chen, Aihua; Zhang, Haizhong; Cao, Hongtao |
出版日期 | 2009 |
会议日期 | OCT 09-12, 2009 |
卷号 | 79-82 |
DOI | 10.4028/www.scientific.net/AMR.79-82.843 |
英文摘要 | Mixed molybdenum-tungsten oxides of varying stoichiometry (MoxW1-x.O3, 0 < x <1) were prepared by sot-gel deposition from peroxo-polymolybdotungstate solutions onto conductive fluorine doped tin oxide (FTO) coated glass substrates. The compositional and structure properties were characterized for MoxWl-xO3 films annealed at 450 degrees C using energy-dispersive spectroscopy and X-ray diffraction measurements. The optical transmittance of the films were recorded with respect to air in the reference beam in a UV-Vis-NIR spectrophotometer. The transmittance modulation of the mixed oxide films were enhanced compared to the pure WO3 film and very broad spectral modulation features were observed for mixed oxide. Cyclic voltammetry and chronoamperometry measurements were conducted to estimate ion storage capacities and reversibility of the films during the coloring/bleaching process for the mixed metal oxide films in an electrolyte solution of lithium perchlorate in propylene carbonate. The subtle interplay between structural and compositional properties due to the uniform mixing of Mo and W oxide components shows that electrochromic and lithium ion transport properties are moderately enhanced relative to those of single-component WO3. |
会议录出版者 | Advanced Materials Research |
学科主题 | Materials Science |
ISSN号 | 1022-6680 |
ISBN号 | 978-0-87849-304-3 |
源URL | [http://ir.nimte.ac.cn/handle/174433/23732] ![]() |
专题 | 会议专题 会议专题_会议论文 |
推荐引用方式 GB/T 7714 | Sun, Xilian,Chen, Aihua,Zhang, Haizhong,et al. Optical and electrochromic properties of sol-gel deposited mixed MoO3-WO3 thin films[C]. 见:. OCT 09-12, 2009. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
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