Visualization of battery materials and their interfaces/interphases using cryogenic electron microscopy
文献类型：期刊论文
| 作者 | Yousaf, Muhammad12; Naseer, Ufra11; Imran, Ali12; Li, Yiju10; Aftab, Waseem10; Mahmood, Asif9; Mahmood, Nasir8; Zhang, Xuan7,12; Gao, Peng5,6; Lu, Yingying4,12 |
| 刊名 | MATERIALS TODAY
 |
| 出版日期 | 2022-09-01 |
| 卷号 | 58页码:238-274 |
| 关键词 | Cryogenic electron microscopy Rechargeable batteries Lithium metal batteries Solid-state electrolytes Solid electrolyte interphase (SEI) |
| ISSN号 | 1369-7021 |
| DOI | 10.1016/j.mattod.2022.06.022 |
| 通讯作者 | Yousaf, Muhammad(muhammadyousaf@zju.edu.cn) ; Lu, Yingying(yingyinglu@zju.edu.cn) ; Guo, Shaojun(guosj@pku.edu.cn) ; Jiang, Yinzhu(yzjiang@zju.edu.cn) |
| 英文摘要 | Future innovations and developments in advanced rechargeable batteries require atomic-scale observation and understanding of the failure mechanisms of secondary batteries. Unfortunately, battery chemistry is highly sensitive to air or moisture and cannot stand electron beam radiation at high dose rates essential for atomic-scale resolution, hence limiting the use of conventional electron or optical microscopes. Recently, cryogenic electron microscopy (cryo-EM) has shown that battery -sensitive materials and interface/interphases can be protected, stabilized, and imaged under cryogenic conditions, facilitating novel insights into key components and phenomena that have a substantial impact on the cell operation. Herein, we highlight the significance and essential role of cryo-EM in characterizing sensitive battery materials (such as Li/Na/K metal anodes, sulfur, lithiated silicon, etc.), key components and interfaces, and summarize the recent contributions and discoveries enabled by cryo-EM. The chemistries and evolving nanostructures at electrode/electrolyte interphase in various electrolytes (both solid and liquid), hosts, artificial interphases, and temperature ranges for lithium -based batteries, and beyond are discussed in detail. Finally, the conclusions and the perspectives on the future direction of cryo-EM in analyzing the battery materials and interfaces are briefly discussed. We believe that the insights and discoveries obtained from this characterizing tool will provide guidelines for developing energy materials with improved electrochemical performance. |
| WOS关键词 | RAY PHOTOELECTRON-SPECTROSCOPY ; LITHIUM METAL BATTERIES ; HIGH-VOLTAGE SPINEL ; CRYO-EM STRUCTURE ; IN-SITU ; SILICON ELECTRODES ; RADIATION-DAMAGE ; ION BATTERIES ; SURFACE-CHEMISTRY ; ATOMIC-STRUCTURE |
| 资助项目 | National Key Research and Development Program[2019YFE0111200] ; Zhejiang Provincial Natural Science Foundation of China[LR18B030001] ; Fundamental Research Funds for the Central Universities[2021- FZZX001-09] ; Univer- sity of Technology Sydney |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000875520100002 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key Research and Development Program ; Zhejiang Provincial Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Univer- sity of Technology Sydney |
| 源URL | [http://ir.igsnrr.ac.cn/handle/311030/186237]  |
| 专题 | 中国科学院地理科学与资源研究所 |
| 通讯作者 | Yousaf, Muhammad; Lu, Yingying; Guo, Shaojun; Jiang, Yinzhu |
| 作者单位 | 1.Baotou Res Inst Rare Earths, State Key Lab Baiyunobo Rare Earth Resource Res &, Baotou 014030, Peoples R China 2.Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China 3.Xian Technol Univ, Inst Sci & Technol New Energy, Xian 710021, Peoples R China 4.Zhejiang Univ, Coll Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Peoples R China 5.Peking Univ, Sch Phys, Electron Microscopy Lab, Beijing 100871, Peoples R China 6.Peking Univ, Sch Phys, Int Ctr Quantum Mat, Beijing 100871, Peoples R China 7.Katholieke Univ Leuven, Dept Mat Engn, Kasteelpk Arenberg 44,Bus 2450, B-3001 Heverlee, Belgium 8.RMIT Univ, Sch Engn, 124 La Trobe St, Melbourne, Vic 3001, Australia 9.Univ Technol Sydney, Ctr Clean Energy Technol, Sch Math & Phys Sci, Sydney, NSW 2007, Australia 10.Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yousaf, Muhammad,Naseer, Ufra,Imran, Ali,et al. Visualization of battery materials and their interfaces/interphases using cryogenic electron microscopy[J]. MATERIALS TODAY,2022,58:238-274. |
| APA | Yousaf, Muhammad.,Naseer, Ufra.,Imran, Ali.,Li, Yiju.,Aftab, Waseem.,...&Jiang, Yinzhu.(2022).Visualization of battery materials and their interfaces/interphases using cryogenic electron microscopy.MATERIALS TODAY,58,238-274. |
| MLA | Yousaf, Muhammad,et al."Visualization of battery materials and their interfaces/interphases using cryogenic electron microscopy".MATERIALS TODAY 58(2022):238-274. |
入库方式： OAI收割
来源：地理科学与资源研究所
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