Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents with Alkenyl Carbonate
文献类型：期刊论文
| 作者 | Qin, Hongjian2,5; Yang, Xingbang3,4; Mintah Bonku, Emmanuel3,5; Zhu, Fuqiang1; Abduahadi, Safomuddin3,5; Yang, Peng4; Shen, Jingshan3,5 ; Akber Aisa, Haji2,5
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| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
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| 出版日期 | 2024-10-31 |
| 页码 | 8 |
| 关键词 | Iron catalysis
Alkylation of alkenyl carbonates
Grignard reagents
Cross-coupling reactions
C( |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.202400979 |
| 英文摘要 | Herein, we report the alkylation of alkenyl carbonates using alkyl Grignard reagents and iron catalysis to generate C(sp2)-C(sp3) bonds and provide synthetically useful yields over a range of substrates. The transformation allows the alkylation of a wide range of substrates, including aromatic rings, alkanes, cycloalkanes, heterocycles. This reaction has introduced a new family of electrophiles to the iron-catalyzed cross-coupling reactions. |
| WOS关键词 | REACTIVITY ; CHLORIDES ; HALIDES ; FE ; NI |
| 资助项目 | West Light Foundation of The Chinese Academy of Sciences ; Special Foundation of Chinese Academy of Sciences for strategic pilot technology ; [2018-XBYJRC-001] |
| WOS研究方向 | Chemistry |
| WOS记录号 | WOS:001345153200001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/314312]  |
| 专题 | 新药研究国家重点实验室 |
| 通讯作者 | Shen, Jingshan; Akber Aisa, Haji |
| 作者单位 | 1.Topharman Shanghai Co Ltd, 388 Jialilue Rd,Zhangjiang Hitech Pk, Shanghai 201203, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Reg, South Beijing Rd 40-1, Urumqi 830011, Xinjiang, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zuchongzhi Rd, Shanghai 201203, Peoples R China 4.Shenyang Pharmaceut Univ, Wuya Coll Innovat, Shenyang 110016, Peoples R China 5.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Hongjian,Yang, Xingbang,Mintah Bonku, Emmanuel,et al. Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents with Alkenyl Carbonate[J]. ADVANCED SYNTHESIS & CATALYSIS,2024:8. |
| APA | Qin, Hongjian.,Yang, Xingbang.,Mintah Bonku, Emmanuel.,Zhu, Fuqiang.,Abduahadi, Safomuddin.,...&Akber Aisa, Haji.(2024).Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents with Alkenyl Carbonate.ADVANCED SYNTHESIS & CATALYSIS,8. |
| MLA | Qin, Hongjian,et al."Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignard Reagents with Alkenyl Carbonate".ADVANCED SYNTHESIS & CATALYSIS (2024):8. |
入库方式： OAI收割
来源：上海药物研究所
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