中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Sources and formation characteristics of atmospheric water-soluble organic carbon in North China: Implications from a one-year background observation

文献类型:期刊论文

作者Yu, Jing2; Sun, Rong3; Li, Yuchen3; Yin, Xuehua3; Zong, Zheng1; Sun, Ling2; Tian, Chongguo3
刊名ATMOSPHERIC ENVIRONMENT
出版日期2025-12-15
卷号363页码:9
关键词WSOC Sources Formation North China Anthropogenic impact
ISSN号1352-2310
DOI10.1016/j.atmosenv.2025.121631
英文摘要

Water-soluble organic carbon (WSOC) is a major carbonaceous component of fine particulate matter (PM2.5), with significant implications for air quality, climate change, and the global carbon cycle. However, limited observational data under regional background condition has hindered a comprehensive understanding of its seasonal variability, sources, and formation pathways, especially in North China. To address this gap, we carried out a year-long observation of WSOC at Beihuangcheng Island, a representative regional background site in North China. The results revealed an annual average WSOC concentration of 2.96 +/- 1.99 mu g m(-3), with marked seasonal variability-higher levels during the cold season and lower levels during the warm season. Strong positive correlations between WSOC and several chemical tracers in PM2.5 (e.g., K+, SO42-) as well as secondary organic carbon (SOC) indicate that WSOC is predominantly of secondary origin, mainly derived from anthropogenic emissions such as coal combustion and biomass burning. Source apportionment using the Positive Matrix Factorization (PMF) model identified secondary aerosol formation as the dominant contributor, accounting for 47.3 % of WSOC annually. This source is characterized by high loads of NO3-, SO42-, and a low organic carbon to elemental carbon (OC/EC) ratio, implicating fossil fuel-related emissions-especially from vehicles and coal combustion-in the secondary formation of WSOC. Biomass burning emerged as the second-largest contributor, responsible for 33.2 % of annual WSOC, with a notable rise to 40.0 % in winter. This seasonal increase highlights the substantial influence of residential heating and agricultural residue burning on WSOC levels during the cold season.

WOS关键词BOHAI RIM ; AEROSOLS ; SITE ; EMISSIONS ; PM2.5
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
语种英语
WOS记录号WOS:001608136300001
源URL[http://ir.yic.ac.cn/handle/133337/41578]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
通讯作者Yu, Jing
作者单位1.Shandong Univ, Environm Res Inst, Qingdao, Shandong, Peoples R China
2.Yantai Vocat Coll, Yantai, Shandong, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai, Shandong, Peoples R China
推荐引用方式
GB/T 7714
Yu, Jing,Sun, Rong,Li, Yuchen,et al. Sources and formation characteristics of atmospheric water-soluble organic carbon in North China: Implications from a one-year background observation[J]. ATMOSPHERIC ENVIRONMENT,2025,363:9.
APA Yu, Jing.,Sun, Rong.,Li, Yuchen.,Yin, Xuehua.,Zong, Zheng.,...&Tian, Chongguo.(2025).Sources and formation characteristics of atmospheric water-soluble organic carbon in North China: Implications from a one-year background observation.ATMOSPHERIC ENVIRONMENT,363,9.
MLA Yu, Jing,et al."Sources and formation characteristics of atmospheric water-soluble organic carbon in North China: Implications from a one-year background observation".ATMOSPHERIC ENVIRONMENT 363(2025):9.

入库方式: OAI收割

来源:烟台海岸带研究所

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