An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging
文献类型：期刊论文
| 作者 | Qin, Zhengbo; Cong, Ran; Liu, Zhiling; Xie, Hua; Tang, Zichao; Fan, Hongjun |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2014-06-07 |
| 卷号 | 140期号:21页码:214318 |
| ISSN号 | 1089-7690 |
| 产权排序 | 待补充 |
| 通讯作者 | 唐紫超 ; 樊红军 |
| 合作状况 | 英 |
| 英文摘要 | low-energy photoelectron imaging spectra of hcs(2)(-)are reported for the first time. vibrationally resolved photodetachment transitions from the ground state of hcs2- to the ground state and low-lying excited states of hcs2 are observed. combined with the ab intio calculations and franck-condon simulations, well-resolved vibrational spectra demonstrate definitive evidence for the resolution of the ground-state and excited states of hcs2 radical in the gaseous phase. the ground state and two low-lying excited states of hcs2 radical are assigned as b-2(2), (2)a(2), and (2)a(1) states, respectively. the adiabatic electron affinity is determined to be 2.910 +/- 0.007 ev. and the term energies of the excited states, t-0 = 0.451 +/- 0.009 ev and 0.553 +/- 0.009 ev, are directly measured from the experimental data, respectively. angular filtering photoelectron spectra are carried out to assist in the spectral band assignment. (c) 2014 aip publishing llc. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | tandem mass-spectrometry ; potential-energy surface ; negative-ions ; infrared-spectra ; carbon-disulfide ; spectroscopy ; hco2 ; density ; anions ; thioformaldehyde |
| 收录类别 | SCI |
| 资助信息 | 1，1 |
| 原文出处 | 214318 |
| 语种 | 英语 |
| WOS记录号 | WOS:000337108900039 |
| 公开日期 | 2014-09-11 |
| 源URL | [http://159.226.238.44/handle/321008/119745]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Zhengbo,Cong, Ran,Liu, Zhiling,et al. An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging[J]. journal of chemical physics,2014,140(21):214318. |
| APA | Qin, Zhengbo,Cong, Ran,Liu, Zhiling,Xie, Hua,Tang, Zichao,&Fan, Hongjun.(2014).An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging.journal of chemical physics,140(21),214318. |
| MLA | Qin, Zhengbo,et al."An investigation into low-lying electronic states of HCS2 via threshold photoelectron imaging".journal of chemical physics 140.21(2014):214318. |
入库方式： OAI收割
来源：大连化学物理研究所
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