Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds
文献类型：期刊论文
| 作者 | Qiu, Min; Hu, Xiang-Ping; Wang, Dao-Yong; Deng, Jun; Huang, Jia-Di; Yu, Sai-Bo; Duan, Zheng-Chao; Zheng, Zhuo |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2008-06-01 |
| 卷号 | 350期号:9页码:1413-1418 |
| 关键词 | asymmetric catalysis hydrogenation olefins phosphine-phosphoramidite ligand |
| 英文摘要 | we have recently reported a new chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand, (r-c,r-a)-thnaphos, that is highly efficient in the rhodium-catalyzed asymmetric hydrogenation of a broad range of alpha-enol ester phosphonates. to further demonstrate the utility of thnaphos in asymmetric hydrogenation, in this paper, we describe its new application in the asymmetric hydrogenation of alpha-dehydroamino acid esters, enamides, dimethyl itaconate and alpha-enamido phosphonates. the results disclosed that the rh/(r-c,r-a)-thnaphos complex is highly effective for the enantioselective hydrogenation of these kinds of functionalized c=c olefins, affording the corresponding hydrogenation product in excellent enantioselectivities (normally over 99% ee). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalyzed asymmetric hydrogenation ; phosphonic acid-derivatives ; alpha-amino ; micellar media ; hydroxy ; complexes ; quinaphos ; esters |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000256976100035 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140797]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Min,Hu, Xiang-Ping,Wang, Dao-Yong,et al. Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds[J]. advanced synthesis & catalysis,2008,350(9):1413-1418. |
| APA | Qiu, Min.,Hu, Xiang-Ping.,Wang, Dao-Yong.,Deng, Jun.,Huang, Jia-Di.,...&Zheng, Zhuo.(2008).Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds.advanced synthesis & catalysis,350(9),1413-1418. |
| MLA | Qiu, Min,et al."Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds".advanced synthesis & catalysis 350.9(2008):1413-1418. |
入库方式： OAI收割
来源：大连化学物理研究所
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