Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations
文献类型：期刊论文
| 作者 | Qiu, Min1,2; Hu, Xiang-Ping1; Huang, Jia-Di1,2; Wang, Dao-Yong1,2; Deng, Jun1,2; Yu, Sai-Bo1,2; Duan, Zheng-Chao1,2; Zheng, Zhuo1 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2008-11-01 |
| 卷号 | 350期号:17页码:2683-2689 |
| 关键词 | asymmetric catalysis hydrogenation phosphine-aminophosphine ligands rhodium 1 2 3 4-tetrahydro-1-naphthylamine |
| 英文摘要 | a series of new chiral phosphine-aminophosphine ligands [(r)-hw-phos] has been prepared from (r)-l.,2,3,4-tetrahydro-1-naphthylamine through a two-step procedure, and successfully applied in the rhodium-catalyzed asymmetric hydrogenation of various functionalized olefins such as alpha-enol ester phosphonates, alpha-enamido phosphonates, (z)-beta-(acylamino)acrylates and so on. excellent enantioselectivities have been achieved in the hydrogenation of most substrates tested, demonstrating the high potential of these newly developed phosphine-aminophosphine ligands in asymmetric catalysis. the present research also discloses that these newly developed phosphine-aminophosphine ligands are more efficient than that derived from (s)-1-phenyl ethyl amine, suggesting that the increased rigidity conferred by a cyclohexyl fragment in these phosphine-aminophosphine ligands has a positive effect in the asymmetric induction. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalyzed asymmetric hydrogenation ; phosphonic acid-derivatives ; enol ester phosphonates ; n-h proton ; micellar media ; alpha-hydroxy ; complexes |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000261485400002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140991]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Min,Hu, Xiang-Ping,Huang, Jia-Di,et al. Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations[J]. advanced synthesis & catalysis,2008,350(17):2683-2689. |
| APA | Qiu, Min.,Hu, Xiang-Ping.,Huang, Jia-Di.,Wang, Dao-Yong.,Deng, Jun.,...&Zheng, Zhuo.(2008).Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations.advanced synthesis & catalysis,350(17),2683-2689. |
| MLA | Qiu, Min,et al."Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations".advanced synthesis & catalysis 350.17(2008):2683-2689. |
入库方式： OAI收割
来源：大连化学物理研究所
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