Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)
文献类型：期刊论文
| 作者 | Chi, Chao-xian2; Xie, Hua1; Cong, Ran1; Tang, Zi-chao1; Zhou, Ming-fei2 |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 24期号:5页码:557-562 |
| 关键词 | Silver methanol complex Solvation Photoelectron imaging Density functional calculation |
| 英文摘要 | the agoch3- and ag-(ch3oh)(x) (x=1, 2) anions are studied by photoelectron imaging as well as ab initio calculations. the adiabatic and vertical detachment energies (ade and vde) of agoch3- are determined as 1.29(2) and 1.34(2) ev, respectively, from the vibrational resolved photoelectron spectrum. the ag-(ch3oh)1,2 anionic complexes are characterized as metal atomic anion solvated by the ch3oh molecules with the electron mainly localized on the metal. the photoelectron spectra of ag-(ch3oh)(x) (x=0, 1, 2) show a gradual increase in vde with increasing x, due to the solvent stabilization. evidence for the methanol-methanol hydrogen bonding interactions appears when the ag- is solvated by two methanol molecules. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | effective core potentials ; liquid methanol ; gas-phase ; ab-initio ; vibrational spectroscopy ; molecular calculations ; solvation dynamics ; electron-affinities ; dilute-solutions ; hcl solvation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297139200009 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142527]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chi, Chao-xian,Xie, Hua,Cong, Ran,et al. Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)[J]. chinese journal of chemical physics,2011,24(5):557-562. |
| APA | Chi, Chao-xian,Xie, Hua,Cong, Ran,Tang, Zi-chao,&Zhou, Ming-fei.(2011).Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2).chinese journal of chemical physics,24(5),557-562. |
| MLA | Chi, Chao-xian,et al."Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)".chinese journal of chemical physics 24.5(2011):557-562. |
入库方式： OAI收割
来源：大连化学物理研究所
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