Photoelectron Imaging of Ag-(H2O)(x) and AgOH-(H2O)(y) (x=1,2, y=0-4)
文献类型：期刊论文
| 作者 | Chi, Chaoxian1; Xie, Hua2; Li, Yuzhen1; Cong, Ran2; Zhou, Mingfei1; Tang, Zichao2 |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2011-06-02 |
| 卷号 | 115期号:21页码:5380-5386 |
| 英文摘要 | the photoelectron images of ag-(h2o)(x) (x = 1,2) and agoh-(h2o)(y) (y = 0-4) are reported. the ag-(h2o)(1,2) anionic complexes have similar characteristics to the other two coinage metal-water complexes that can be characterized as metal atomic anion solvated by water molecules with the electron mainly localized on the metal. the vibrationally well-resolved photoelectron spectrum allows the adiabatic detachment energy (ade) and vertical detachment energy (vde) of agoh- to be determined as 1.18(2) and 1.24(2) ev, respectively. the agoh- anion interacts more strongly with water molecules than the ag- anion. the photoelectron spectra of ag-(h2o)(x) and agoh-(h2o)(y) show a gradual increase in ade and vde with increasing x and y due to the solvent stabilization. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | transition-metal hydroxides ; effective core potentials ; cluster negative-ions ; der-waals complexes ; ab-initio ; molecular calculations ; infrared-spectroscopy ; electron-affinities ; weak-interactions ; water clusters |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000290914500017 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142618]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chi, Chaoxian,Xie, Hua,Li, Yuzhen,et al. Photoelectron Imaging of Ag-(H2O)(x) and AgOH-(H2O)(y) (x=1,2, y=0-4)[J]. journal of physical chemistry a,2011,115(21):5380-5386. |
| APA | Chi, Chaoxian,Xie, Hua,Li, Yuzhen,Cong, Ran,Zhou, Mingfei,&Tang, Zichao.(2011).Photoelectron Imaging of Ag-(H2O)(x) and AgOH-(H2O)(y) (x=1,2, y=0-4).journal of physical chemistry a,115(21),5380-5386. |
| MLA | Chi, Chaoxian,et al."Photoelectron Imaging of Ag-(H2O)(x) and AgOH-(H2O)(y) (x=1,2, y=0-4)".journal of physical chemistry a 115.21(2011):5380-5386. |
入库方式： OAI收割
来源：大连化学物理研究所
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