Nafion/polyvinylidene fluoride blend membranes with improved ion selectivity for vanadium redox flow battery application
文献类型：期刊论文
| 作者 | Mai, Zhensheng1,2; Zhang, Huamin1; Li, Xianfeng1; Xiao, Shaohua1,2; Zhang, Hongzhang1,2 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2011-07-01 |
| 卷号 | 196期号:13页码:5737-5741 |
| 关键词 | Polymer blends Ion exchange membranes Vanadium redox flow battery |
| 英文摘要 | nafion/pvdf blends are employed to prepare the ion exchange membranes for vanadium redox flow battery (vrb) application for the first time. the addition of the highly crystalline and hydrophobic pvdf effectively confines the swelling behavior of nafion. in vrb single cell test, the nafion/pvdf binary membranes exhibit higher columbic efficiency than recast nafion at various current densities. the blend membrane with 20 wt% of pvdf (n(0.8)p(0.2)) shows energy efficiency of 85% at 80 ma cm(-2), which is superior to that of recast nafion. n(0.8)p(0.2) membrane also possesses twice longer duration in ocv decay test and much lower permeation of vo(2+) compared with recast nafion. these results indicate that the addition of pvdf is a simple and efficient way to improve the ion selectivity of nafion, and the polymer blends with optimized mass fraction of pvdf show good potential for vrb application. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | methanol fuel-cells ; poly(vinylidene fluoride) ; nafion membrane ; perfluorosulfonate ionomer ; miscibility ; performance |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291144000049 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142727]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, PEMFC Key Mat & Technol Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mai, Zhensheng,Zhang, Huamin,Li, Xianfeng,et al. Nafion/polyvinylidene fluoride blend membranes with improved ion selectivity for vanadium redox flow battery application[J]. journal of power sources,2011,196(13):5737-5741. |
| APA | Mai, Zhensheng,Zhang, Huamin,Li, Xianfeng,Xiao, Shaohua,&Zhang, Hongzhang.(2011).Nafion/polyvinylidene fluoride blend membranes with improved ion selectivity for vanadium redox flow battery application.journal of power sources,196(13),5737-5741. |
| MLA | Mai, Zhensheng,et al."Nafion/polyvinylidene fluoride blend membranes with improved ion selectivity for vanadium redox flow battery application".journal of power sources 196.13(2011):5737-5741. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。