中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
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CAS IR Grid
机构
大连化学物理研究所 [2]
中国科学院大学 [1]
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期刊论文 [3]
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2019 [1]
2018 [1]
2016 [1]
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Palladium-catalyzed propargylic [n+2] cycloaddition: an efficient strategy for construction of benzo-fused medium-sized heterocycles
期刊论文
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Advanced synthesis & catalysis, 2019, 卷号: 361, 期号: 4, 页码: 836-841
作者:
Liu, Zhen-Ting
;
Hu, Xiang-Ping
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浏览/下载:78/0
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提交时间:2019/05/08
A regioselective palladium-catalyzed formal [n+2] cycloaddition of propargylic esters as c-2-synthons with various linker-tethered bisphenols for the construction of medium-sized heterocycles bearing an exocyclic double bond has been developed
The reaction features mild conditions and broad substrate scopes
As well as readily available substrates and catalysts
Under optimal conditions
Various medium-sized heterocycles from eight to eleven-membered rings can be afforded in good to excellent yields and regioselectivities with high z-selectivity for the exocyclic double bond
Palladium
Medium-sized ring
Propargylic ester
Bisphenol
Cycloaddition
Rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and co
期刊论文
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Angewandte chemie-international edition, 2018, 卷号: 57, 期号: 47, 页码: 15544-15548
作者:
Tian, Zi-You
;
Cui, Qi
;
Liu, Cheng-Hang
;
Yu, Zhi-Xiang
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浏览/下载:39/0
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提交时间:2019/05/08
Conjugation
Cycloaddition
Fused-ring systems
Reaction mechanisms
Rhodium
Fungal biotransformation of tanshinone results in [4+2] cycloaddition with sorbicillinol: evidence for enzyme catalysis and increased antibacterial activity
期刊论文
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Applied microbiology and biotechnology, 2016, 卷号: 100, 期号: 19, 页码: 8349-8357
作者:
He, Wenni
;
Liu, Miaomiao
;
Li, Xiaolin
;
Zhang, Xiaoping
;
Abdel-Mageed, Wael M.
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浏览/下载:48/0
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提交时间:2019/05/09
Biotransformation
[4+2] cycloaddition reaction
Tanshinone iia
Hypocrea sp