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机构
大连化学物理研究所 [4]
化学研究所 [1]
长春应用化学研究所 [1]
兰州化学物理研究所 [1]
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OAI收割 [6]
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期刊论文 [7]
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2019 [2]
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学科主题
分析化学与药物化学 [1]
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Palladium-Catalyzed Propargylic [n+2] Cycloaddition: An Efficient Strategy for Construction of Benzo-Fused Medium-Sized Heterocycles
期刊论文
OAI收割
ADVANCED SYNTHESIS & CATALYSIS, 2019, 卷号: 361, 期号: 4, 页码: 836-841
作者:
Liu, Zhen-Ting
;
Hu, Xiang-Ping
  |  
收藏
  |  
浏览/下载:67/0
  |  
提交时间:2019/06/20
A regioselective palladium-catalyzed formal [n+2] cycloaddition of propargylic esters as C-2-synthons with various linker-tethered bisphenols for the construction of medium-sized heterocycles bearing an exocyclic double bond has been developed
The reaction features mild conditions and broad substrate scopes
as well as readily available substrates and catalysts
Under optimal conditions
various medium-sized heterocycles from eight to eleven-membered rings can be afforded in good to excellent yields and regioselectivities with high Z-selectivity for the exocyclic double bond
palladium
medium-sized ring
propargylic ester
bisphenol
cycloaddition
Palladium-catalyzed propargylic [n+2] cycloaddition: an efficient strategy for construction of benzo-fused medium-sized heterocycles
期刊论文
iSwitch采集
Advanced synthesis & catalysis, 2019, 卷号: 361, 期号: 4, 页码: 836-841
作者:
Liu, Zhen-Ting
;
Hu, Xiang-Ping
收藏
  |  
浏览/下载:91/0
  |  
提交时间:2019/05/08
A regioselective palladium-catalyzed formal [n+2] cycloaddition of propargylic esters as c-2-synthons with various linker-tethered bisphenols for the construction of medium-sized heterocycles bearing an exocyclic double bond has been developed
The reaction features mild conditions and broad substrate scopes
As well as readily available substrates and catalysts
Under optimal conditions
Various medium-sized heterocycles from eight to eleven-membered rings can be afforded in good to excellent yields and regioselectivities with high z-selectivity for the exocyclic double bond
Palladium
Medium-sized ring
Propargylic ester
Bisphenol
Cycloaddition
Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions
期刊论文
OAI收割
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2016, 卷号: 12, 页码: 796-804
作者:
Qiu, Di
;
Zhang, Yan
;
Wang, Jianbo
;
Wang, Bo
  |  
收藏
  |  
浏览/下载:25/0
  |  
提交时间:2019/06/20
Alkane
Diazo Compounds
C-h Bond Functionalization
C-h Bond Insertion
Metal-carbene
Site-selectivity
Cutting a chemical bond with demon's scissors: Mode- and bond-selective reactivity of methane on metal surfaces
期刊论文
OAI收割
surface science, 2015, 卷号: 640, 页码: 25-35
作者:
Lozano, A.
;
Shen, X. J.
;
Moiraghi, R.
;
Dong, W.
;
Busnengo, H. F.
收藏
  |  
浏览/下载:30/0
  |  
提交时间:2015/11/17
Methane
Surfaces
Molecular dynamics
Adsorption
Reactive force fields
Bond selectivity
Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst
期刊论文
OAI收割
journal of molecular catalysis a-chemical, 2014, 卷号: 395, 页码: 1-6
Li, Xiaoru
;
Zhang, Chao
;
Cheng, Haiyang
;
He,Limin
;
Lin,Weiwei
;
Yu,Yancun
;
Zhao,Fengyu
收藏
  |  
浏览/下载:87/0
  |  
提交时间:2015/10/20
Nickel based catalyst is of interest in the industrial catalytic processes
and it is always modified by doping a second element to improve its catalytic properties. Understanding the role of dopant is extremely helpful in tailoring the active centers. In this work
Zn could induce a significant improvement of the catalytic performance of NiAl for the hydrogenolysis of glycerol. The Zn doped ZnNiAl catalysts exhibited high activity and the improved selectivity to 1
2-propanediol
it was about 2 times higher than the original ones. The ZnNi alloy formed in ZnNiAl was responsible for the noticeable catalytic performance. They preferred to coordinate with the end hydroxyl group of glycerol
promoted the cleavage of C-O bond in glycerol
and resulted in the dominant formation of 1
2-propanediol. The findings described here will provide a useful knowledge for rational design of nickel-based catalysts
as well as reveal a new reaction model for the hydrogenolysis of glycerol. (C) 2014 Elsevier B.V. All rights reserved.
Anion binding and sensing properties of bis(3-indolyl)methene derivatives based on proton transfer process
期刊论文
OAI收割
Letters in Organic Chemistry, 2011, 卷号: 8, 期号: 1, 页码: 60-65
作者:
Shao SJ(邵士俊)
;
Xu J(徐健)
;
Guo Y(郭勇)
;
Wang LT(王利涛)
;
Shao SJ(邵士俊)
收藏
  |  
浏览/下载:48/0
  |  
提交时间:2012/10/18
Anion recognition
bis(3-indolyl)methene
colorimetric chemosensor
hydrogen bond
proton transfer
tunable selectivity and sensitivity
Synthesis, Characterization and Single Crystal Structure of 4-iso-Butoxy-10-hydroxy-1,7-phenanthroline-2,8-dicarboxylic Acid Dimethyl Ester
期刊论文
OAI收割
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2010, 卷号: 30, 期号: 11, 页码: 1716-1720
作者:
Zhu Hengheng
;
Guan Zisheng
;
Zhan Chuanlang
  |  
收藏
  |  
浏览/下载:21/0
  |  
提交时间:2019/04/09
Synthetic Selectivity
Intramolecular Hydrogen-bond
Mitsunobu Reaction
Crystal Structure