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Water oxidation on a mononuclear manganese heterogeneous catalyst 期刊论文  OAI收割
NATURE CATALYSIS, 2018, 卷号: 1, 期号: 11, 页码: 870-877
作者:  
Guan, JQ;  Duan, ZY;  Zhang, FX;  Kelly, SD;  Si, R
  |  收藏  |  浏览/下载:37/0  |  提交时间:2019/12/17
Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst 期刊论文  OAI收割
journal of molecular catalysis a-chemical, 2014, 卷号: 395, 页码: 1-6
Li, Xiaoru; Zhang, Chao; Cheng, Haiyang; He,Limin; Lin,Weiwei; Yu,Yancun; Zhao,Fengyu
收藏  |  浏览/下载:91/0  |  提交时间:2015/10/20
Nickel based catalyst is of interest in the industrial catalytic processes  and it is always modified by doping a second element to improve its catalytic properties. Understanding the role of dopant is extremely helpful in tailoring the active centers. In this work  Zn could induce a significant improvement of the catalytic performance of NiAl for the hydrogenolysis of glycerol. The Zn doped ZnNiAl catalysts exhibited high activity and the improved selectivity to 1  2-propanediol  it was about 2 times higher than the original ones. The ZnNi alloy formed in ZnNiAl was responsible for the noticeable catalytic performance. They preferred to coordinate with the end hydroxyl group of glycerol  promoted the cleavage of C-O bond in glycerol  and resulted in the dominant formation of 1  2-propanediol. The findings described here will provide a useful knowledge for rational design of nickel-based catalysts  as well as reveal a new reaction model for the hydrogenolysis of glycerol. (C) 2014 Elsevier B.V. All rights reserved.  
Transition-metal-catalyzed Suzuki-Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts 期刊论文  OAI收割
chemical society reviews, 2013, 卷号: 42, 期号: 12, 页码: 5270-5298
Han FS
收藏  |  浏览/下载:37/0  |  提交时间:2014/04/18
Nickel-Catalyzed Cross-Coupling of Phenols and Arylboronic Acids Through an In Situ Phenol Activation Mediated by PyBroP 期刊论文  OAI收割
chemistry-a european journal, 2011, 卷号: 17, 期号: 14, 页码: 4038-4042
Chen GJ; Huang J; Gao LX; Han FS
收藏  |  浏览/下载:36/0  |  提交时间:2012/06/11