中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
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CAS IR Grid
机构
长春应用化学研究所 [3]
化学研究所 [2]
过程工程研究所 [1]
生态环境研究中心 [1]
广州能源研究所 [1]
采集方式
OAI收割 [8]
内容类型
期刊论文 [8]
发表日期
2021 [1]
2020 [1]
2017 [2]
2014 [2]
2010 [2]
学科主题
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Elucidating the Active Site and the Role of Alkali Metals in Selective Hydrodeoxygenation of Phenols over Iron-Carbide-based Catalyst
期刊论文
OAI收割
CHEMSUSCHEM, 2021, 卷号: 14, 期号: 20, 页码: 4546-4555
作者:
Zhang, Jianghao
  |  
收藏
  |  
浏览/下载:24/0
  |  
提交时间:2021/12/23
alkali metals
C-O bond cleavage
graphene
iron carbide
tautomerism
Lowering the pyrolysis temperature of lignocellulosic biomass by H2SO4 loading for enhancing the production of platform chemicals
期刊论文
OAI收割
CHEMICAL ENGINEERING JOURNAL, 2020, 卷号: 385, 页码: 8
作者:
Cao, Fengzhu
;
Xia, Shengpeng
;
Yang, Xingwei
;
Wang, Chenyang
;
Wang, Qi
  |  
收藏
  |  
浏览/下载:33/0
  |  
提交时间:2020/10/29
Biomass
Controlled pyrolysis
C-O bond cleavage
Anhydrosugar
Low temperature
Reductive Cleavage of C-O Bond in Model Compounds of Lignin
期刊论文
OAI收割
CHINESE JOURNAL OF CHEMISTRY, 2017, 卷号: 35, 期号: 6, 页码: 938-942
作者:
Xu, Huanjun
;
Liu, Xinwei
;
Zhao, Yanfei
;
Wu, Cailing
;
Chen, Yu
  |  
收藏
  |  
浏览/下载:36/0
  |  
提交时间:2018/04/11
Lignin
C-o Bond
Aryl Ethers
Reductive Cleavage
Aromatics
Mechanism of Organophosphonate Catabolism by Diiron Oxygenase PhnZ: A Third Iron-Mediated O-O Activation Scenario in Nature
期刊论文
OAI收割
ACS CATALYSIS, 2017, 卷号: 7, 期号: 5, 页码: 3521-3531
作者:
Zhao, Chongyang
;
Chen, Hui
  |  
收藏
  |  
浏览/下载:38/0
  |  
提交时间:2018/01/24
C-p Bond Cleavage
Qm/mm
Diiron Enzyme
Superoxo
Heterolytic O-o Cleavage
Organophosphonate Catabolism
Ferric-peroxide
Phosphorus Oxidation
Highly efficient, NiAu-catalyzed hydrogenolysis of lignin into phenolic chemicals
期刊论文
OAI收割
GREEN CHEMISTRY, 2014, 卷号: 16, 期号: 5, 页码: 2432-2437
作者:
Zhang, Jiaguang
;
Asakura, Hiroyuki
;
van Rijn, Jeaphianne
;
Yang, Jun
;
Duchesne, Paul
收藏
  |  
浏览/下载:36/0
  |  
提交时间:2014/08/28
GAS-PHASE HYDROGENATION
ALUMINA-SUPPORTED AU
O BOND-CLEAVAGE
ARYL
ETHERS
STYRENE HYDROGENATION
RENEWABLE CHEMICALS
NICKEL-CATALYSTS
M-DINITROBENZENE
ETHYLENE-GLYCOL
MODEL COMPOUNDS
Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst
期刊论文
OAI收割
journal of molecular catalysis a-chemical, 2014, 卷号: 395, 页码: 1-6
Li, Xiaoru
;
Zhang, Chao
;
Cheng, Haiyang
;
He,Limin
;
Lin,Weiwei
;
Yu,Yancun
;
Zhao,Fengyu
收藏
  |  
浏览/下载:87/0
  |  
提交时间:2015/10/20
Nickel based catalyst is of interest in the industrial catalytic processes
and it is always modified by doping a second element to improve its catalytic properties. Understanding the role of dopant is extremely helpful in tailoring the active centers. In this work
Zn could induce a significant improvement of the catalytic performance of NiAl for the hydrogenolysis of glycerol. The Zn doped ZnNiAl catalysts exhibited high activity and the improved selectivity to 1
2-propanediol
it was about 2 times higher than the original ones. The ZnNi alloy formed in ZnNiAl was responsible for the noticeable catalytic performance. They preferred to coordinate with the end hydroxyl group of glycerol
promoted the cleavage of C-O bond in glycerol
and resulted in the dominant formation of 1
2-propanediol. The findings described here will provide a useful knowledge for rational design of nickel-based catalysts
as well as reveal a new reaction model for the hydrogenolysis of glycerol. (C) 2014 Elsevier B.V. All rights reserved.
Mechanistic insight into alcohol oxidation mediated by an efficient green Cu-II-bipy catalyst with and without TEMPO by density functional methods
期刊论文
OAI收割
dalton transactions, 2010, 卷号: 39, 期号: 22, 页码: 5377-5387
Cheng L
;
Wang JP
;
Wang MY
;
Wu ZJ
收藏
  |  
浏览/下载:24/0
  |  
提交时间:2012/06/06
SELECTIVE AEROBIC OXIDATION
O BOND-CLEAVAGE
OXIDASE MODEL COMPLEXES
GALACTOSE-OXIDASE
ELECTRONIC-STRUCTURE
END-ON
COPPER(II) COMPLEXES
THEORETICAL EVIDENCE
2-STATE REACTIVITY
MONONUCLEAR COPPER
Mechanistic Insight into the Alcohol Oxidation Mediated by an Efficient Green [CuBr2(2,2 '-bipy)]-TEMPO Catalyst by Density Functional Method
期刊论文
OAI收割
inorganic chemistry, 2010, 卷号: 49, 期号: 20, 页码: 9392-9399
Cheng L
;
Wang JP
;
Wang MY
;
Wu ZJ
收藏
  |  
浏览/下载:33/0
  |  
提交时间:2012/04/25
O BOND-CLEAVAGE
GALACTOSE-OXIDASE
AEROBIC OXIDATION
2-STATE REACTIVITY
END-ON
THEORETICAL EVIDENCE
ELECTRONIC-STRUCTURE
MONONUCLEAR COPPER
ACTIVE-SITE
COMPOUND-I