中国科学院机构知识库网格
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Effect of Zn doping on the hydrogenolysis of glycerol over ZnNiAl catalyst 期刊论文  OAI收割
journal of molecular catalysis a-chemical, 2014, 卷号: 395, 页码: 1-6
Li, Xiaoru; Zhang, Chao; Cheng, Haiyang; He,Limin; Lin,Weiwei; Yu,Yancun; Zhao,Fengyu
收藏  |  浏览/下载:87/0  |  提交时间:2015/10/20
Nickel based catalyst is of interest in the industrial catalytic processes  and it is always modified by doping a second element to improve its catalytic properties. Understanding the role of dopant is extremely helpful in tailoring the active centers. In this work  Zn could induce a significant improvement of the catalytic performance of NiAl for the hydrogenolysis of glycerol. The Zn doped ZnNiAl catalysts exhibited high activity and the improved selectivity to 1  2-propanediol  it was about 2 times higher than the original ones. The ZnNi alloy formed in ZnNiAl was responsible for the noticeable catalytic performance. They preferred to coordinate with the end hydroxyl group of glycerol  promoted the cleavage of C-O bond in glycerol  and resulted in the dominant formation of 1  2-propanediol. The findings described here will provide a useful knowledge for rational design of nickel-based catalysts  as well as reveal a new reaction model for the hydrogenolysis of glycerol. (C) 2014 Elsevier B.V. All rights reserved.  
Nuclear spin induced collapse and revival shape of Rabi oscillations of a single electron spin in diamond 期刊论文  OAI收割
CHINESE PHYSICS B, 2011, 卷号: 20, 期号: 11
Hu, X; Liu, DQ; Pan, XY
收藏  |  浏览/下载:30/0  |  提交时间:2013/09/24
Origin of the 330 nm absorption band and effect of doping yb in liyf4 crystals 期刊论文  iSwitch采集
Journal of luminescence, 2010, 卷号: 130, 期号: 8, 页码: 1338-1342
作者:  
Yin, Jigang;  Hang, Yin;  Zhang, Lianhan;  Zhao, Chengchun;  Xiong, Jing
收藏  |  浏览/下载:38/0  |  提交时间:2019/05/10
Electron paramagnetic resonance parameters of V2+ ions in both Cd2+ sites of CsCdCl3 crystal 期刊论文  OAI收割
Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy, 2002, 卷号: 58, 期号: 1, 页码: 79-82
W. C. Zheng; S. Y. Wu
收藏  |  浏览/下载:18/0  |  提交时间:2012/04/14
Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals 期刊论文  OAI收割
Physica B-Condensed Matter, 1998, 卷号: 253, 期号: 1-2, 页码: 79-82
W. C. Zheng; S. Y. Wu; W. Li
收藏  |  浏览/下载:23/0  |  提交时间:2012/04/14
New color centers and luminescence of BaFI:Eu2+ 期刊论文  OAI收割
chinese science bulletin, 1997, 卷号: 42, 期号: 15, 页码: 1268-1271
Chen W; Su MZ
收藏  |  浏览/下载:15/0  |  提交时间:2010/11/17
Electron migration in BaFCl:Eu2+ phosphors 期刊论文  OAI收割
journal of applied physics, 1997, 卷号: 81, 期号: 7, 页码: 3170-3174
Chen W; Song QQ; Su MZ
收藏  |  浏览/下载:30/0  |  提交时间:2010/11/17