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Chinese Academy of Sciences Institutional Repositories Grid
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CAS IR Grid
机构
福建物质结构研究所 [3]
采集方式
OAI收割 [3]
内容类型
期刊论文 [3]
发表日期
2011 [3]
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A glycine ligand coordinated hybrid complex constructed from hexanuclear copper clusters and octamolybdates
期刊论文
OAI收割
Inorganic Chemistry Communications, 2011, 卷号: 14, 期号: 9, 页码: 1546-1549
X. Y. Jiang
;
X. Y. Wu
;
R. M. Yu
;
D. Q. Yuan
;
W. Z. Chen
收藏
  |  
浏览/下载:31/0
  |  
提交时间:2012/06/06
Self-assembly of the sodium molybdate
copper chloride and glycine in
aqueous solution results in a novel
compound
{(NaCu(6)(Gly)(8)(H(2)O)(2)][Mo(8)O(26)(GlyH)(2)(Cu(Gly)H(2)O)](2)}{NaCu
(6)(Gly)(8)(H(2)O)(2)}{
Mo(8)O(26)(GlyH)(2))center dot 16H(2)O (1).
Compound 1 contains a new unit of
{[NaCu(6)(Gly)(8)(H(2)O)(2)][Mo(8)O(26)Cu(Gly)(2)I(2))
in
which the
[Mo(8)O(26)Cu(Gly)(2)] polyoxometalate units are connected by the
[NaCu(6)(Gly)(8)(H(2)O)(2)] hexanuclear
copper cluster. The magnetic
measurement of 1 shows that ferromagnetic coupling exists between the
magnetic centers of the hexanuclear copper cluster. (C) 2011 Elsevier BV
All rights reserved.
building units
polyoxometalate
chemistry
polymer
oxides
A 2D polyoxometalate-based complex: spin-canting and metamagnetism
期刊论文
OAI收割
Crystengcomm, 2011, 卷号: 13, 期号: 11, 页码: 3686-3688
X. Y. Wu
;
P. Dong
;
R. M. Yu
;
Q. K. Zhang
;
X. F. Kuang
;
S. C. Chen
;
Q. P. Lin
;
C. Z. Lu
收藏
  |  
浏览/下载:37/0
  |  
提交时间:2012/06/06
single-molecule magnets
coordination polymers
hydrothermal synthesis
weak ferromagnetism
crystal-structures
metal-complexes
co-ii
frameworks
octamolybdates
tetrazolate
Inorganic-organic hybrid compounds based on molybdenum oxide chains and tetrazolate-bridged polymeric silver cations
期刊论文
OAI收割
Dalton Transactions, 2011, 卷号: 40, 期号: 9, 页码: 1866-1872
M. X. Yang
;
L. J. Chen
;
S. Lin
;
X. H. Chen
;
H. Huang
收藏
  |  
浏览/下载:23/0
  |  
提交时间:2012/06/06
hydrothermal synthesis
coordination polymer
building-blocks
crystal-structure
frameworks
chemistry
octamolybdates
subunits
clusters
solids