Tert-butanesulfinylphosphines: simple chiral ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins
文献类型：期刊论文
| 作者 | Lang, Feng1,2; Li, Dong1,2; Chen, Junmin1,2,3; Chen, Jun1,2; Li, Liangchun1; Cun, Linfeng1; Zhu, Jin1; Deng, Jingen1,2; Liao, Jian1,2 |
| 刊名 | Advanced synthesis & catalysis
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 352期号:5页码:843-846 |
| 关键词 | 1,4-addition Asymmetric catalysis Rhodium complexes S-chirality Tert-butanesulfinylphosphine ligand |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.200900792 |
| 通讯作者 | Liao, jian(jliao10@cioc.ac.cn) |
| 英文摘要 | An efficient rhodium complex catalyst system was developed by using a class of simple tert-butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. excellent activities (in 0.5 hour, up to 99% yield) and enantioselectivities (up to 98% ee) were displayed in rh-catalyzed asymmetric 1,4-additions under mild conditions. |
| WOS关键词 | NUCLEOPHILIC-SUBSTITUTION REACTIONS ; BORONIC ACIDS ; CONJUGATE ADDITIONS ; DIENE LIGANDS ; 1,4-ADDITION REACTIONS ; SULFOXIDE COMPLEXES ; HIGH-PERFORMANCE ; CYCLOALKENONES ; P,N-LIGANDS ; VERSATILE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Applied ; Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000276317800006 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2410927 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liao, Jian |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lang, Feng,Li, Dong,Chen, Junmin,et al. Tert-butanesulfinylphosphines: simple chiral ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins[J]. Advanced synthesis & catalysis,2010,352(5):843-846. |
| APA | Lang, Feng.,Li, Dong.,Chen, Junmin.,Chen, Jun.,Li, Liangchun.,...&Liao, Jian.(2010).Tert-butanesulfinylphosphines: simple chiral ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins.Advanced synthesis & catalysis,352(5),843-846. |
| MLA | Lang, Feng,et al."Tert-butanesulfinylphosphines: simple chiral ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to electron-deficient olefins".Advanced synthesis & catalysis 352.5(2010):843-846. |
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来源：中国科学院大学
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