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大连化学物理研究所 [2]
过程工程研究所 [2]
长春应用化学研究所 [2]
化学研究所 [1]
烟台海岸带研究所 [1]
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OAI收割 [8]
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期刊论文 [8]
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2019 [1]
2015 [1]
2011 [1]
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食用蔬菜能吸收和积累微塑料
期刊论文
OAI收割
科学通报, 2019, 卷号: 64, 期号: 9, 页码: 928-934
作者:
李连祯
;
周倩
;
尹娜
;
涂晨
;
骆永明
  |  
收藏
  |  
浏览/下载:147/0
  |  
提交时间:2020/06/17
微塑料
生菜
聚苯乙烯微球
吸收
积累
健康风险
microplastics
lettuce
polystyrene microbeads
uptake
accumulation
human health risk
Microplastic (MP, 100 nm-5 mm) may present an attributable risk to ecosystem and human health, and its pollution has become a global environmental concern. Despite a wealth of information on the accumulation of MPs in aquatic species, there is no information on the uptake and accumulation of MPs by higher plants. Terrestrial edible plants are directly exposed to MPs when agricultural soil was applied with organic manure, sewage sludge as fertilizer or plastic mulching. In this paper, the uptake of two sizes of polystyrene (PS) microbeads (0.2 and 1.0 mum) and then their distribution and migration in an edible plant lettuce were firstly investigated based on laboratory experiments. We used fluorescent markers to track PS microbeads in plant tissues and found fluorescence to be a sensitive and reliable detection method. Sections from untreated control lettuce showed no autofluorescence. When roots were treated with fluorescently labeled PS microbeads, the microbeads could be identified by its fluorescence. Our main study investigated the uptake of 0.2 mum beads, as few luminescence signals were observed in lettuce roots for 1.0 mum beads in our experiment. We observed that 0.2 mum fluorescent microbeads were extracellularly trapped in the root cap mucilage (which is a highly hydrated polysaccharide) and a dark green tip (which was typical of lettuce roots exposed to label PS beads) was usually visible to the naked eye. Confocal images revealed that the PS luminescence signals were mainly located in the vascular system and on the cell walls of the cortex tissue of the roots, indicated that the beads passed through the intercellular space via the apoplastic transport system. Once inside the central cylinder, the 0.2 mum PS beads were transferred from the roots to the stems and leaves via the vascular system following the transpiration stream. We also observed that the PS beads adhered to one another and self-assembled systematically into grape-like and (chain) string-like clusters in the intercellular space of the root and stem vascular tissue of lettuce plant. In contrast to the root and stem, PS beads were dispersed in the leaf tissue. Here, for the first time we provide evidence of the adherence, uptake, accumulation, and translocation of submicrometer MPs within an edible plant. Our findings highlight the previously underappreciated human exposure pathway to MPs through the consumption of contaminated crops and emphasize the need for new management strategies to control the release of MPs waste products into the terrestrial environment. Ultimately, the potential impacts of low range sized MPs on food safety of crop plants and human health need to be urgently considered.
Preparation and characterization of a thermoresponsive gigaporous medium for high-speed protein chromatography
期刊论文
OAI收割
Analytica Chimica Acta, 2015, 期号: 0, 页码: 617-624
作者:
Qu, J. B.
;
Chen, Y. L.
;
Huan, G. S.
;
Zhou, W. Q.
;
Liu, J. G.
收藏
  |  
浏览/下载:31/0
  |  
提交时间:2015/04/01
Gigaporous polystyrene microspheres
Thermoresponsive polymer brushes
Protein chromatography
N-isopropylacrylamide
Atom transfer radical
polymerization
POLYSTYRENE MICROSPHERES
AQUEOUS CHROMATOGRAPHY
LIQUID-CHROMATOGRAPHY
STATIONARY-PHASE
SEPARATION
POLYMERS
SILICA
BEADS
A Solid Homogeneous Zirconocene Catalyst from Cp(2)ZrCl(2) Supported on Porous Polymer Particles
期刊论文
OAI收割
journal of polymer science part a-polymer chemistry, 2011, 卷号: 49, 期号: 6, 页码: 1503-1507
Lei JH
;
Li DL
;
Wang HH
;
Wang ZQ
;
Zhou GY
收藏
  |  
浏览/下载:52/0
  |  
提交时间:2012/06/11
ALPHA-OLEFIN POLYMERIZATION
CROSS-LINKED POLYSTYRENE
ETHYLENE POLYMERIZATION
METALLOCENE CATALYSTS
RAC-PH2SI(IND)(2)ZRCL2 CATALYST
FUNCTIONALIZED POLYSTYRENE
PROPENE POLYMERIZATION
BEADS
STEREOSPECIFICITY
COMPLEXES
Monodispersed Magnetic Polystyrene Beads with Excellent Colloidal Stability and Strong Magnetic Response
期刊论文
OAI收割
MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 卷号: 31, 期号: 20, 页码: 1805-1810
作者:
Niu, Mu
;
Du, Meihong
;
Gao, Zhenyu
;
Yang, Chunhui
;
Lu, Xianyong
  |  
收藏
  |  
浏览/下载:11/0
  |  
提交时间:2019/04/09
Colloidal Stability
Magnetic Response
Monodispersed Magnetic Beads
Polymerization
Polystyrene
Surface-modified polystyrene beads as photografting imprinted polymer matrix for chromatographic separation of proteins
期刊论文
OAI收割
journal of chromatography a, 2009, 卷号: 1216, 期号: 5, 页码: 807-814
作者:
Qin, Lei
;
He, Xi-Wen
;
Zhang, Wei
;
Li, Wen-You
收藏
  |  
浏览/下载:28/0
  |  
提交时间:2010/11/30
Molecular imprinting
Protein separation
Polystyrene beads
Iniferter
Chromatography
Effective heterogenization and catalytic use of active C(5)H(5)NiLX complex for the hydrosilylation
期刊论文
OAI收割
catalysis communications, 2008, 卷号: 9, 期号: 8, 页码: 1793-1798
作者:
Xu, Z.
;
Lu, X. -H.
;
Xia, Q. -H.
;
Lou, Z. -W.
;
Ye, C. -P.
收藏
  |  
浏览/下载:30/0
  |  
提交时间:2015/11/12
polystyrene beads
immobilization
heterogeneous solid nickel complex catalyst
hydrosilylation
Preparative purification of polyethylene glycol derivatives with polystyrene-divinylbenzene beads as chromatographic packing
期刊论文
OAI收割
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2007, 卷号: 17, 期号: 20, 页码: 5605-5609
作者:
Yu, Pengzhan
;
Li, Xingqi
;
Li, Xiunan
;
Lu, Xiuling
;
Ma, Guanghui
收藏
  |  
浏览/下载:80/0
  |  
提交时间:2013/10/15
polystyrene-divinyl benzene beads
purification of polyethylene glycol derivatives
preparative reversed-phase chromatography
Effect of swelling response of the support particles on ethylene polymerization
期刊论文
OAI收割
polymer, 2007, 卷号: 48, 期号: 9, 页码: 2481-2488
Shi LY
;
Qin YX
;
Cheng WX
;
Chen H
;
Tang T
收藏
  |  
浏览/下载:18/0
  |  
提交时间:2010/07/13
METALLOCENE CATALYSTS
OLEFIN POLYMERIZATION
PROPYLENE POLYMERIZATION
POLY(STYRENE-CO-DIVINYLBENZENE) BEADS
RAC-PH2SI(IND)(2)ZRCL2 CATALYST
PHASE POLYMERIZATION
KINETIC-ANALYSIS
ZIEGLER-NATTA
POLYSTYRENE
FRAGMENTATION